Oxidative properties of a nonheme Ni(ii)(O 2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation

Reza Latifi; Laleh Tahsini; Devesh Kumar; G. Narahari Sastry; Wonwoo Nam; Sam P. De Visser

doi:10.1039/c1cc13993b

Oxidative properties of a nonheme Ni(ii)(O 2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation

Reza Latifi, Laleh Tahsini, Devesh Kumar, G. Narahari Sastry, Wonwoo Nam, Sam P. De Visser

Research output: Contribution to journal › Article › peer-review

Abstract

Density functional theory calculations on the reactivity of a Ni(ii)-superoxo complex in C-H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(ii)-superoxo complex is able to react with substrates with weak C-H bonds and PPh 3. © 2011 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	10674-10676
Number of pages	2
Journal	Chemical Communications
Volume	47
Issue number	38
DOIs	https://doi.org/10.1039/c1cc13993b
Publication status	Published - 14 Oct 2011

Access to Document

10.1039/c1cc13993b

http://www.scopus.com/inward/record.url?eid=2-s2.0-80052946740&partnerID=40&md5=e0b94e5aa5fe8d8b35eb60aae2ef7d9a

Cite this

@article{de2a0d8eec904358a0cec36f420a77c8,

title = "Oxidative properties of a nonheme Ni(ii)(O 2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation",

abstract = "Density functional theory calculations on the reactivity of a Ni(ii)-superoxo complex in C-H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(ii)-superoxo complex is able to react with substrates with weak C-H bonds and PPh 3. {\textcopyright} 2011 The Royal Society of Chemistry.",

author = "Reza Latifi and Laleh Tahsini and Devesh Kumar and Sastry, {G. Narahari} and Wonwoo Nam and {De Visser}, {Sam P.}",

note = "cited By 11",

year = "2011",

month = oct,

day = "14",

doi = "10.1039/c1cc13993b",

language = "English",

volume = "47",

pages = "10674--10676",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "38",

}

TY - JOUR

T1 - Oxidative properties of a nonheme Ni(ii)(O 2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation

AU - Latifi, Reza

AU - Tahsini, Laleh

AU - Kumar, Devesh

AU - Sastry, G. Narahari

AU - Nam, Wonwoo

AU - De Visser, Sam P.

N1 - cited By 11

PY - 2011/10/14

Y1 - 2011/10/14

N2 - Density functional theory calculations on the reactivity of a Ni(ii)-superoxo complex in C-H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(ii)-superoxo complex is able to react with substrates with weak C-H bonds and PPh 3. © 2011 The Royal Society of Chemistry.

AB - Density functional theory calculations on the reactivity of a Ni(ii)-superoxo complex in C-H bond activation, aromatic hydroxylation and heteroatom oxidation reactions have been explored; the Ni(ii)-superoxo complex is able to react with substrates with weak C-H bonds and PPh 3. © 2011 The Royal Society of Chemistry.

U2 - 10.1039/c1cc13993b

DO - 10.1039/c1cc13993b

M3 - Article

SN - 1359-7345

VL - 47

SP - 10674

EP - 10676

JO - Chemical Communications

JF - Chemical Communications

IS - 38

ER -

Oxidative properties of a nonheme Ni(ii)(O 2) complex: Reactivity patterns for C-H activation, aromatic hydroxylation and heteroatom oxidation

Abstract

Access to Document

Fingerprint

Cite this