Oxygen-vacancy sites on TiO2(100)1×3 using surface core-level-shift photoelectron diffraction

P. J. Hardman, N. S. Prakash, C. A. Muryn, G. N. Raikar, A. G. Thomas, A. F. Prime, G. Thornton, R. J. Blake

Research output: Contribution to journalArticlepeer-review

Abstract

Surface core-level-shift photoelectron diffraction has been used to determine the position of oxygen vacancies on rutile TiO2(100)1×3. Ti 3p photoelectrons associated with Ti atoms adjacent to oxygen vacancies were used as the diffraction source. The angle-scanning mode at fixed photon energy was employed to provide maximum surface sensitivity. By comparison with multiple-scattering calculations, the data indicate that vacancies are located in the topmost layer of a microfacet structure proposed on the basis of grazing-incidence x-ray diffraction data.

Original languageEnglish
Pages (from-to)16056-16059
Number of pages4
JournalPhysical Review B
Volume47
Issue number23
DOIs
Publication statusPublished - 1993

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