Palladium mediated spiroketal synthesis: Application to pheromone synthesis

Jeremy C. Conway, Peter Quayle, Andrew C. Regan, Christopher J. Urch

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Stereospecific Stille coupling reactions of 2-metallo-dihydropyrans with Z-vinyl iodo alcohols and subsequent cyclisation provides rapid access to 1,7-dioxaspiro[5.5]undecane family of spiroketals. © 2005 Elsevier Ltd. All rights reserved.
    Original languageEnglish
    Pages (from-to)11910-11923
    Number of pages13
    JournalTetrahedron
    Volume61
    Issue number50
    DOIs
    Publication statusPublished - 12 Dec 2005

    Keywords

    • Palladium
    • Selenium
    • Spiroketal
    • Stille
    • Stork
    • Vinyl iodide

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