Parallel interpenetration in novel herringbone sheets formed by Co(II) and Cd(II) complexes with trans-4,4'-azobis(pyridine)

Martin Schroder, M A Withersby, M Schröder, A J Blake, P A Champness, P Cooke, P Hubberstey

    Research output: Contribution to journalArticlepeer-review

    Abstract

    The complexes {[M2(µ-4,4′-apy)3(NO3)4]·CH2Cl2}= (1, M=Co; 2 M=Cd; 4,4′-apy=trans-4,4′-azobis(pyridine)) form interpenetrated 2-D grids with a (6,3) topology. These sheets exhibit a new herringbone motif in which Co(II) or Cd(II) centres are bridged by co-ordinated 4,4′-apy ligands.
    Original languageEnglish
    Pages (from-to)573-575
    Number of pages3
    JournalNew Journal of Chemistry
    Volume23
    Issue number6
    DOIs
    Publication statusPublished - 1999

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