Pathways for decomposition of THF by organolithiums: The role of HMPA

Jonathan Clayden; Samreen A. Yasin

doi:10.1039/b109604d

Pathways for decomposition of THF by organolithiums: The role of HMPA

Jonathan Clayden, Samreen A. Yasin

Research output: Contribution to journal › Article › peer-review

Abstract

The decomposition of THF by organolithiums in the presence of HMPA gives lithium but-3-en-1-oxide by a reverse 5-endo-trig ring opening.

Original language	English
Pages (from-to)	191-192
Number of pages	1
Journal	New Journal of Chemistry
Volume	26
Issue number	2
DOIs	https://doi.org/10.1039/b109604d
Publication status	Published - 2002

Keywords

Ring opening (decompn. of THF by organolithiums in presence of HMPA)

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10.1039/b109604d

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title = "Pathways for decomposition of THF by organolithiums: The role of HMPA",

abstract = "The decomposition of THF by organolithiums in the presence of HMPA gives lithium but-3-en-1-oxide by a reverse 5-endo-trig ring opening.",

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year = "2002",

doi = "10.1039/b109604d",

language = "English",

volume = "26",

pages = "191--192",

journal = "New Journal of Chemistry",

issn = "1369-9261",

publisher = "Royal Society of Chemistry",

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AU - Clayden, Jonathan

AU - Yasin, Samreen A.

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AB - The decomposition of THF by organolithiums in the presence of HMPA gives lithium but-3-en-1-oxide by a reverse 5-endo-trig ring opening.

KW - Ring opening (decompn. of THF by organolithiums in presence of HMPA)

U2 - 10.1039/b109604d

DO - 10.1039/b109604d

M3 - Article

SN - 1369-9261

VL - 26

SP - 191

EP - 192

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 2

ER -

Pathways for decomposition of THF by organolithiums: The role of HMPA

Abstract

Keywords

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