Pb and Bi valencies in BaPb1-xBixO3

Wendy R. Flavell; Belinda C. Morris; Ian Tweddell; Douglas Purdie; Geoff Thornton; Paul L. Wincott; Robert L. Bilsborrow

Pb and Bi valencies in BaPb1-xBixO3

Wendy R. Flavell, Belinda C. Morris, Ian Tweddell, Douglas Purdie, Geoff Thornton, Paul L. Wincott, Robert L. Bilsborrow

Research output: Contribution to journal › Article › peer-review

Abstract

Near-edge X-ray absorption spectroscopy (XAS) measurements for BaPb 1-xBixO3 have been made across the entire solid-solution range at the Bi LIII, and Pb LIII, absorption edges. By the use of appropriate standards, we infer that whereas the Pb valency in the material remains 'PbIV-like', the Bi valency increases as lead is doped into BaBiO3.

Original language	English
Pages (from-to)	1209-1210
Number of pages	1
Journal	Journal of Materials Chemistry
Volume	2
Issue number	11
Publication status	Published - 1992

Keywords

BaBi1-xPbxO3
Bi valency
Liii edge
X-ray absorption spectroscopy

Cite this

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title = "Pb and Bi valencies in BaPb1-xBixO3",

abstract = "Near-edge X-ray absorption spectroscopy (XAS) measurements for BaPb 1-xBixO3 have been made across the entire solid-solution range at the Bi LIII, and Pb LIII, absorption edges. By the use of appropriate standards, we infer that whereas the Pb valency in the material remains 'PbIV-like', the Bi valency increases as lead is doped into BaBiO3.",

keywords = "BaBi1-xPbxO3, Bi valency, Liii edge, X-ray absorption spectroscopy",

author = "Flavell, {Wendy R.} and Morris, {Belinda C.} and Ian Tweddell and Douglas Purdie and Geoff Thornton and Wincott, {Paul L.} and Bilsborrow, {Robert L.}",

year = "1992",

language = "English",

volume = "2",

pages = "1209--1210",

journal = "Journal of Materials Chemistry",

issn = "0959-9428",

publisher = "Royal Society of Chemistry",

number = "11",

}

TY - JOUR

T1 - Pb and Bi valencies in BaPb1-xBixO3

AU - Flavell, Wendy R.

AU - Morris, Belinda C.

AU - Tweddell, Ian

AU - Purdie, Douglas

AU - Thornton, Geoff

AU - Wincott, Paul L.

AU - Bilsborrow, Robert L.

PY - 1992

Y1 - 1992

N2 - Near-edge X-ray absorption spectroscopy (XAS) measurements for BaPb 1-xBixO3 have been made across the entire solid-solution range at the Bi LIII, and Pb LIII, absorption edges. By the use of appropriate standards, we infer that whereas the Pb valency in the material remains 'PbIV-like', the Bi valency increases as lead is doped into BaBiO3.

AB - Near-edge X-ray absorption spectroscopy (XAS) measurements for BaPb 1-xBixO3 have been made across the entire solid-solution range at the Bi LIII, and Pb LIII, absorption edges. By the use of appropriate standards, we infer that whereas the Pb valency in the material remains 'PbIV-like', the Bi valency increases as lead is doped into BaBiO3.

KW - BaBi1-xPbxO3

KW - Bi valency

KW - Liii edge

KW - X-ray absorption spectroscopy

M3 - Article

VL - 2

SP - 1209

EP - 1210

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

SN - 0959-9428

IS - 11

ER -

Pb and Bi valencies in BaPb1-xBixO3

Abstract

Keywords

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