Phase behaviour of methylcellulose-poly(acrylic acid) blends and preparation of related hydrophilic films

Vitaliy V. Khutoryanskiy; Maria Grazia Cascone; Luigi Lazzeri; Zauresh S. Nurkeeva; Grigoriy A. Mun; Rauash A. Mangazbaeva

doi:10.1002/pi.1004

Phase behaviour of methylcellulose-poly(acrylic acid) blends and preparation of related hydrophilic films

Vitaliy V. Khutoryanskiy, Maria Grazia Cascone, Luigi Lazzeri, Zauresh S. Nurkeeva, Grigoriy A. Mun, Rauash A. Mangazbaeva

Research output: Contribution to journal › Article › peer-review

Abstract

The phase behavior of methylcellulose-poly(acrylic acid) mixtures was studied in aqueous solution. It was shown that the complexation between the two polymers decreases considerably the cloud-point of methylcellulose. The addition of inorganic salts shifts the critical pH values toward a higher pH region. Films were prepared based on methylcellulose-poly(acrylic acid) blends and were analyzed by dynamic mechanical thermal analysis, scanning electron microscopy and thermal gravimetric analysis. The miscibility between the two polymers in the films was shown. It was found that the thermal treatment of the films leads to their cross-linking with the formation of materials swellable both in water and ethanol. © 2003 Society of Chemical Industry.

Original language	English
Pages (from-to)	62-67
Number of pages	5
Journal	Polymer International
Volume	52
Issue number	1
DOIs	https://doi.org/10.1002/pi.1004
Publication status	Published - Jan 2003

Keywords

Interpolymer complexes
Miscible blends
Polysaccharides

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10.1002/pi.1004

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title = "Phase behaviour of methylcellulose-poly(acrylic acid) blends and preparation of related hydrophilic films",

abstract = "The phase behavior of methylcellulose-poly(acrylic acid) mixtures was studied in aqueous solution. It was shown that the complexation between the two polymers decreases considerably the cloud-point of methylcellulose. The addition of inorganic salts shifts the critical pH values toward a higher pH region. Films were prepared based on methylcellulose-poly(acrylic acid) blends and were analyzed by dynamic mechanical thermal analysis, scanning electron microscopy and thermal gravimetric analysis. The miscibility between the two polymers in the films was shown. It was found that the thermal treatment of the films leads to their cross-linking with the formation of materials swellable both in water and ethanol. {\textcopyright} 2003 Society of Chemical Industry.",

keywords = "Interpolymer complexes, Miscible blends, Polysaccharides",

author = "Khutoryanskiy, {Vitaliy V.} and Cascone, {Maria Grazia} and Luigi Lazzeri and Nurkeeva, {Zauresh S.} and Mun, {Grigoriy A.} and Mangazbaeva, {Rauash A.}",

year = "2003",

month = jan,

doi = "10.1002/pi.1004",

language = "English",

volume = "52",

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journal = "Polymer International",

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T1 - Phase behaviour of methylcellulose-poly(acrylic acid) blends and preparation of related hydrophilic films

AU - Khutoryanskiy, Vitaliy V.

AU - Cascone, Maria Grazia

AU - Lazzeri, Luigi

AU - Nurkeeva, Zauresh S.

AU - Mun, Grigoriy A.

AU - Mangazbaeva, Rauash A.

PY - 2003/1

Y1 - 2003/1

N2 - The phase behavior of methylcellulose-poly(acrylic acid) mixtures was studied in aqueous solution. It was shown that the complexation between the two polymers decreases considerably the cloud-point of methylcellulose. The addition of inorganic salts shifts the critical pH values toward a higher pH region. Films were prepared based on methylcellulose-poly(acrylic acid) blends and were analyzed by dynamic mechanical thermal analysis, scanning electron microscopy and thermal gravimetric analysis. The miscibility between the two polymers in the films was shown. It was found that the thermal treatment of the films leads to their cross-linking with the formation of materials swellable both in water and ethanol. © 2003 Society of Chemical Industry.

AB - The phase behavior of methylcellulose-poly(acrylic acid) mixtures was studied in aqueous solution. It was shown that the complexation between the two polymers decreases considerably the cloud-point of methylcellulose. The addition of inorganic salts shifts the critical pH values toward a higher pH region. Films were prepared based on methylcellulose-poly(acrylic acid) blends and were analyzed by dynamic mechanical thermal analysis, scanning electron microscopy and thermal gravimetric analysis. The miscibility between the two polymers in the films was shown. It was found that the thermal treatment of the films leads to their cross-linking with the formation of materials swellable both in water and ethanol. © 2003 Society of Chemical Industry.

KW - Interpolymer complexes

KW - Miscible blends

KW - Polysaccharides

U2 - 10.1002/pi.1004

DO - 10.1002/pi.1004

M3 - Article

SN - 0959-8103

VL - 52

SP - 62

EP - 67

JO - Polymer International

JF - Polymer International

IS - 1

ER -

Phase behaviour of methylcellulose-poly(acrylic acid) blends and preparation of related hydrophilic films

Abstract

Keywords

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