Phenomenological kinetic model of the synthesis of glycerol carbonate assisted by focused beam reflectance measurements

In this paper, the synthesis of glycerol carbonate from glycerol and dimethyl carbonate is studied. First, operating conditions and a catalyst were selected after screening of different alkali metal salts, resulting K2CO3 the most active species. Afterwards, given the low degree of miscibility between the reactants, a study of the phase change from a liquid-liquid emulsion to a monophasic sample throughout the reaction was successfully performed with the aid of a focused beam reflectance probe. This change took place at a conversion of approximately 0.30. With the findings of this study, distinct kinetic models were proposed and fitted to the experimental data obtained after the completion of a series of kinetic runs varying temperature (66-70°C), molar ratio of dimethyl carbonate to glycerol (1.5-3) and catalyst load (0.75-1.25% w/w). A model composed of two potential equations was proposed with activation energy of 179.2±3.7kJmol-1. The model was capable of describing the initial biphasic stage and the monophasic regime correlated best to the experimental data, with errors below 6.8%. © 2014 Published by Elsevier B.V.