Phosphonates as ligands in Co-Cr heterometallic clusters

Yan Zhen Zheng, Barbara A. Breeze, Grigore A. Timco, Floriana Tuna, Richard E P Winpenny

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    Abstract

    Two new Co(ii)-Cr(iii) phosphonate clusters with [CoII 4CrIII4] and [CoII 8CrIII4] cores have been synthesized by a displacement reaction from a pre-formed heterometallic carboxylate cage. Magnetic studies show overall antiferromagnetic interactions are present in these clusters. © 2010 The Royal Society of Chemistry.
    Original languageEnglish
    Pages (from-to)6175-6177
    Number of pages2
    JournalDalton Transactions
    Volume39
    Issue number27
    DOIs
    Publication statusPublished - 2010

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