Phosphonates as ligands in Co-Cr heterometallic clusters

Yan Zhen Zheng; Barbara A. Breeze; Grigore A. Timco; Floriana Tuna; Richard E P Winpenny

doi:10.1039/c0dt00017e

Phosphonates as ligands in Co-Cr heterometallic clusters

Yan Zhen Zheng, Barbara A. Breeze, Grigore A. Timco, Floriana Tuna, Richard E P Winpenny

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Abstract

Two new Co(ii)-Cr(iii) phosphonate clusters with [CoII 4CrIII4] and [CoII 8CrIII4] cores have been synthesized by a displacement reaction from a pre-formed heterometallic carboxylate cage. Magnetic studies show overall antiferromagnetic interactions are present in these clusters. © 2010 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	6175-6177
Number of pages	2
Journal	Dalton Transactions
Volume	39
Issue number	27
DOIs	https://doi.org/10.1039/c0dt00017e
Publication status	Published - 2010

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CCDC 929328: Experimental Crystal Structure Determination
Zheng, Y. Z. (Contributor), Breeze, B. A. (Contributor), Timco, G. (Contributor), Tuna, F. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/cc1061bl, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1061bl&sid=DataCite
Dataset
CCDC 767252: Experimental Crystal Structure Determination
Zheng, Y. Z. (Contributor), Breeze, B. A. (Contributor), Timco, G. (Contributor), Tuna, F. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/cctrd20, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cctrd20&sid=DataCite
Dataset
CCDC 767251: Experimental Crystal Structure Determination
Zheng, Y. Z. (Contributor), Breeze, B. A. (Contributor), Timco, G. (Contributor), Tuna, F. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/cctrd1z, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cctrd1z&sid=DataCite
Dataset

Cite this

@article{0224af53586841638c9ef20f1a2bc9df,

title = "Phosphonates as ligands in Co-Cr heterometallic clusters",

abstract = "Two new Co(ii)-Cr(iii) phosphonate clusters with [CoII 4CrIII4] and [CoII 8CrIII4] cores have been synthesized by a displacement reaction from a pre-formed heterometallic carboxylate cage. Magnetic studies show overall antiferromagnetic interactions are present in these clusters. {\textcopyright} 2010 The Royal Society of Chemistry.",

author = "Zheng, {Yan Zhen} and Breeze, {Barbara A.} and Timco, {Grigore A.} and Floriana Tuna and Winpenny, {Richard E P}",

year = "2010",

doi = "10.1039/c0dt00017e",

language = "English",

volume = "39",

pages = "6175--6177",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "27",

}

TY - JOUR

T1 - Phosphonates as ligands in Co-Cr heterometallic clusters

AU - Zheng, Yan Zhen

AU - Breeze, Barbara A.

AU - Timco, Grigore A.

AU - Tuna, Floriana

AU - Winpenny, Richard E P

PY - 2010

Y1 - 2010

N2 - Two new Co(ii)-Cr(iii) phosphonate clusters with [CoII 4CrIII4] and [CoII 8CrIII4] cores have been synthesized by a displacement reaction from a pre-formed heterometallic carboxylate cage. Magnetic studies show overall antiferromagnetic interactions are present in these clusters. © 2010 The Royal Society of Chemistry.

AB - Two new Co(ii)-Cr(iii) phosphonate clusters with [CoII 4CrIII4] and [CoII 8CrIII4] cores have been synthesized by a displacement reaction from a pre-formed heterometallic carboxylate cage. Magnetic studies show overall antiferromagnetic interactions are present in these clusters. © 2010 The Royal Society of Chemistry.

U2 - 10.1039/c0dt00017e

DO - 10.1039/c0dt00017e

M3 - Article

VL - 39

SP - 6175

EP - 6177

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 27

ER -

Phosphonates as ligands in Co-Cr heterometallic clusters

Abstract

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Datasets

CCDC 929328: Experimental Crystal Structure Determination

CCDC 767252: Experimental Crystal Structure Determination

CCDC 767251: Experimental Crystal Structure Determination

Cite this