Photoinduced formation of gold nanoparticles into vinyl alcohol based polymers

Andrea Pucci, Marco Bernabò, Paolo Elvati, L. Itzel Meza, Fernando Galembeck, Carlos Alberto De Paula Leite, Nicola Tirelli, Giacomo Ruggeri

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Nanocomposites based on vinyl alcohol-containing polymers and nanostructured gold have been efficiently prepared by a UV photo-reduction process. The very fast process provided dispersed gold nanoparticles with average diameters ranging from 3 to 20 nm depending on the host polymer matrix and the irradiation time. Uniaxial drawing of the irradiated Au/polymer nanocomposites favours the anisotropic distribution of packed assemblies of gold particles, providing oriented films with polarization-dependent tunable optical properties. These pronounced dichroic properties suggest that the nanocomposite films could find potential applications as colour polarizing filters, radiation responsive polymeric objects and smart flexible films in packaging applications. © The Royal Society of Chemistry 2006.
    Original languageEnglish
    Pages (from-to)1058-1066
    Number of pages8
    JournalJournal of Materials Chemistry
    Volume16
    Issue number11
    DOIs
    Publication statusPublished - 2006

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