Photoinduced Ru-Yb energy transfer and sensitised near-IR luminescence in a coordination polymer containing co-crystallised [Ru(bipy)(CN)4] 2- and Yb(III) units

Thomas A. Miller; John C. Jeffery; Michael D. Ward; Harry Adams; Simon J A Pope; Stephen Faulkner

doi:10.1039/b404820b

Photoinduced Ru-Yb energy transfer and sensitised near-IR luminescence in a coordination polymer containing co-crystallised [Ru(bipy)(CN)4] 2- and Yb(III) units

Thomas A. Miller, John C. Jeffery, Michael D. Ward, Harry Adams, Simon J A Pope, Stephen Faulkner

Research output: Contribution to journal › Article › peer-review

Abstract

Co-crystallisation of the anionic cyanometallate chromophore [Ru(bipy)(CN)4]2- with Yb(III) provides coordination polymers or oligomers containing Ru-CN-Yb bridges; in [K(H2O) 4][Yb(H2O)6][Ru(bipy)(CN)4] 2·5H2O Ru → Yb energy-transfer (k > 5 × 106 s-1) results in partial quenching of the Ru-based luminescence and sensitised near-IR luminescence from the Yb(III) unit.

Original language	English
Pages (from-to)	1524-1526
Number of pages	2
Journal	Dalton Transactions
Issue number	10
DOIs	https://doi.org/10.1039/b404820b
Publication status	Published - 21 May 2004

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10.1039/b404820b

CCDC 235083: Experimental Crystal Structure Determination
Miller, T. A. (Contributor), Jeffery, J. C. (Contributor), Ward, M. D. (Contributor), Adams, H. (Contributor), Pope, S. J. A. (Contributor) & Faulkner, S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2004
DOI: 10.5517/cc7wmb1, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7wmb1&sid=DataCite
Dataset
CCDC 235084: Experimental Crystal Structure Determination
Miller, T. A. (Contributor), Jeffery, J. C. (Contributor), Ward, M. D. (Contributor), Adams, H. (Contributor), Pope, S. J. A. (Contributor) & Faulkner, S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2004
DOI: 10.5517/cc7wmc2, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc7wmc2&sid=DataCite
Dataset

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@article{ed431ae5a76043208517857f29099f59,

title = "Photoinduced Ru-Yb energy transfer and sensitised near-IR luminescence in a coordination polymer containing co-crystallised [Ru(bipy)(CN)4] 2- and Yb(III) units",

abstract = "Co-crystallisation of the anionic cyanometallate chromophore [Ru(bipy)(CN)4]2- with Yb(III) provides coordination polymers or oligomers containing Ru-CN-Yb bridges; in [K(H2O) 4][Yb(H2O)6][Ru(bipy)(CN)4] 2·5H2O Ru → Yb energy-transfer (k > 5 × 106 s-1) results in partial quenching of the Ru-based luminescence and sensitised near-IR luminescence from the Yb(III) unit.",

author = "Miller, {Thomas A.} and Jeffery, {John C.} and Ward, {Michael D.} and Harry Adams and Pope, {Simon J A} and Stephen Faulkner",

year = "2004",

month = may,

day = "21",

doi = "10.1039/b404820b",

language = "English",

pages = "1524--1526",

journal = "Dalton Transactions",

issn = "1477-9234",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Photoinduced Ru-Yb energy transfer and sensitised near-IR luminescence in a coordination polymer containing co-crystallised [Ru(bipy)(CN)4] 2- and Yb(III) units

AU - Miller, Thomas A.

AU - Jeffery, John C.

AU - Ward, Michael D.

AU - Adams, Harry

AU - Pope, Simon J A

AU - Faulkner, Stephen

PY - 2004/5/21

Y1 - 2004/5/21

N2 - Co-crystallisation of the anionic cyanometallate chromophore [Ru(bipy)(CN)4]2- with Yb(III) provides coordination polymers or oligomers containing Ru-CN-Yb bridges; in [K(H2O) 4][Yb(H2O)6][Ru(bipy)(CN)4] 2·5H2O Ru → Yb energy-transfer (k > 5 × 106 s-1) results in partial quenching of the Ru-based luminescence and sensitised near-IR luminescence from the Yb(III) unit.

AB - Co-crystallisation of the anionic cyanometallate chromophore [Ru(bipy)(CN)4]2- with Yb(III) provides coordination polymers or oligomers containing Ru-CN-Yb bridges; in [K(H2O) 4][Yb(H2O)6][Ru(bipy)(CN)4] 2·5H2O Ru → Yb energy-transfer (k > 5 × 106 s-1) results in partial quenching of the Ru-based luminescence and sensitised near-IR luminescence from the Yb(III) unit.

U2 - 10.1039/b404820b

DO - 10.1039/b404820b

M3 - Article

SN - 1477-9234

SP - 1524

EP - 1526

JO - Dalton Transactions

JF - Dalton Transactions

IS - 10

ER -

Photoinduced Ru-Yb energy transfer and sensitised near-IR luminescence in a coordination polymer containing co-crystallised [Ru(bipy)(CN)4] 2- and Yb(III) units

Abstract

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Datasets

CCDC 235083: Experimental Crystal Structure Determination

CCDC 235084: Experimental Crystal Structure Determination

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