Polarization Dependent High Energy Resolution X-ray Absorption Study of Dicesium Uranyl Tetrachloride

Tonya Vitova; Jennifer C Green; Robert G Denning; Matthias Löble; Kristina Kvashnina; Joshua J Kas; Kevin Jorissen; John J Rehr; Thomas Malcherek; Melissa A Denecke

doi:10.1021/ic5020016

Polarization Dependent High Energy Resolution X-ray Absorption Study of Dicesium Uranyl Tetrachloride

Tonya Vitova
, Jennifer C Green
, Robert G Denning
, Matthias Löble
, Kristina Kvashnina
, Joshua J Kas
, Kevin Jorissen
, John J Rehr
, Thomas Malcherek
, Melissa A Denecke

Dalton Nuclear Institute

Research output: Contribution to journal › Article › peer-review

Abstract

This study confirms theoretically predicted electronic transitions to U 6d xy (6dδ) orbital and measures relative energies of U 5fδ, 5fϕ, 5fπ, and 5fσ orbitals of oriented uranyl (UVIO22+) in the same spectrum with remarkable energy resolution. The demonstrated experimental approach provides means for increased precision in prediction of actinide reactivity important, for example, for developing diagnostics in medical applications.

Original language	English
Pages (from-to)	174-182
Number of pages	8
Journal	Inorganic Chemistry: including bioinorganic chemistry
Volume	54
Issue number	1
DOIs	https://doi.org/10.1021/ic5020016
Publication status	Published - 8 Dec 2014

Research Highlights, Institutes and Platforms

Dalton Nuclear Institute

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10.1021/ic5020016

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title = "Polarization Dependent High Energy Resolution X-ray Absorption Study of Dicesium Uranyl Tetrachloride",

abstract = "This study confirms theoretically predicted electronic transitions to U 6d xy (6dδ) orbital and measures relative energies of U 5fδ, 5fϕ, 5fπ, and 5fσ orbitals of oriented uranyl (UVIO22+) in the same spectrum with remarkable energy resolution. The demonstrated experimental approach provides means for increased precision in prediction of actinide reactivity important, for example, for developing diagnostics in medical applications.",

author = "Tonya Vitova and Green, \{Jennifer C\} and Denning, \{Robert G\} and Matthias L{\"o}ble and Kristina Kvashnina and Kas, \{Joshua J\} and Kevin Jorissen and Rehr, \{John J\} and Thomas Malcherek and Denecke, \{Melissa A\}",

year = "2014",

month = dec,

day = "8",

doi = "10.1021/ic5020016",

language = "English",

volume = "54",

pages = "174--182",

journal = "Inorganic Chemistry: including bioinorganic chemistry ",

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publisher = "American Chemical Society",

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T1 - Polarization Dependent High Energy Resolution X-ray Absorption Study of Dicesium Uranyl Tetrachloride

AU - Vitova, Tonya

AU - Green, Jennifer C

AU - Denning, Robert G

AU - Löble, Matthias

AU - Kvashnina, Kristina

AU - Kas, Joshua J

AU - Jorissen, Kevin

AU - Rehr, John J

AU - Malcherek, Thomas

AU - Denecke, Melissa A

PY - 2014/12/8

Y1 - 2014/12/8

N2 - This study confirms theoretically predicted electronic transitions to U 6d xy (6dδ) orbital and measures relative energies of U 5fδ, 5fϕ, 5fπ, and 5fσ orbitals of oriented uranyl (UVIO22+) in the same spectrum with remarkable energy resolution. The demonstrated experimental approach provides means for increased precision in prediction of actinide reactivity important, for example, for developing diagnostics in medical applications.

AB - This study confirms theoretically predicted electronic transitions to U 6d xy (6dδ) orbital and measures relative energies of U 5fδ, 5fϕ, 5fπ, and 5fσ orbitals of oriented uranyl (UVIO22+) in the same spectrum with remarkable energy resolution. The demonstrated experimental approach provides means for increased precision in prediction of actinide reactivity important, for example, for developing diagnostics in medical applications.

U2 - 10.1021/ic5020016

DO - 10.1021/ic5020016

M3 - Article

SN - 0020-1669

VL - 54

SP - 174

EP - 182

JO - Inorganic Chemistry: including bioinorganic chemistry

JF - Inorganic Chemistry: including bioinorganic chemistry

IS - 1

ER -

Polarization Dependent High Energy Resolution X-ray Absorption Study of Dicesium Uranyl Tetrachloride

Abstract

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