Polyelectrolyte Complexes of Linear Copolymers and Hydrogels Based on 2-[(Methacryloyloxy)ethyl]trimethylammonium Chloride and N-Isopropylacrylamide

Vitaliy Khutoryanskiy; Grigoriy A. Mun; Vitaliy V. Khutoryanskiy; Zauresh S. Nurkeeva; Aibek D. Sergaziyev; Natalia A. Fefelova; Janusz M. Rosiak

doi:10.1002/polb.20051

Polyelectrolyte Complexes of Linear Copolymers and Hydrogels Based on 2-[(Methacryloyloxy)ethyl]trimethylammonium Chloride and N-Isopropylacrylamide

Vitaliy Khutoryanskiy, Grigoriy A. Mun, Vitaliy V. Khutoryanskiy, Zauresh S. Nurkeeva, Aibek D. Sergaziyev, Natalia A. Fefelova, Janusz M. Rosiak

Research output: Contribution to journal › Article › peer-review

Abstract

The formation of polyelectrolyte complexes of linear copolymers and hydrogels based on copolymers of 2-[(methacryloyloxy)ethyl]trimethylammonium chloride with N-isopropylacrylamide (MADQUAT-NIPAAM) and poly(acrylic acid) (PAA) has been studied. The composition of the copolymer has been found to affect the composition of the polyelectrolyte complexes significantly, and the molecular weight of PAA influences their aggregation stability. Hydrogels of MADQUAT-NIPAAM immersed in solutions of PAA undergo contraction because of the formation of gel-polymer complexes. The rate of contraction and the final swelling degree of the gel-polymer complexes depend on the concentration of PAA in solution and its molecular weight. © 2004 Wiley Periodicals, Inc.

Original language	English
Pages (from-to)	1506-1513
Number of pages	7
Journal	Journal of Polymer Science, Part B: Polymer Physics
Volume	42
Issue number	8
DOIs	https://doi.org/10.1002/polb.20051
Publication status	Published - 15 Apr 2004

Keywords

Hydrogels
Poly(acrylic acid)
Polyelectrolyte complexes
Quaternary ammonium groups
Swelling
Water-soluble polymers

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10.1002/polb.20051

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Khutoryanskiy, V., Mun, G. A., Khutoryanskiy, V. V., Nurkeeva, Z. S., Sergaziyev, A. D., Fefelova, N. A., & Rosiak, J. M. (2004). Polyelectrolyte Complexes of Linear Copolymers and Hydrogels Based on 2-[(Methacryloyloxy)ethyl]trimethylammonium Chloride and N-Isopropylacrylamide. Journal of Polymer Science, Part B: Polymer Physics, 42(8), 1506-1513. https://doi.org/10.1002/polb.20051

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title = "Polyelectrolyte Complexes of Linear Copolymers and Hydrogels Based on 2-[(Methacryloyloxy)ethyl]trimethylammonium Chloride and N-Isopropylacrylamide",

abstract = "The formation of polyelectrolyte complexes of linear copolymers and hydrogels based on copolymers of 2-[(methacryloyloxy)ethyl]trimethylammonium chloride with N-isopropylacrylamide (MADQUAT-NIPAAM) and poly(acrylic acid) (PAA) has been studied. The composition of the copolymer has been found to affect the composition of the polyelectrolyte complexes significantly, and the molecular weight of PAA influences their aggregation stability. Hydrogels of MADQUAT-NIPAAM immersed in solutions of PAA undergo contraction because of the formation of gel-polymer complexes. The rate of contraction and the final swelling degree of the gel-polymer complexes depend on the concentration of PAA in solution and its molecular weight. {\textcopyright} 2004 Wiley Periodicals, Inc.",

keywords = "Hydrogels, Poly(acrylic acid), Polyelectrolyte complexes, Quaternary ammonium groups, Swelling, Water-soluble polymers",

author = "Vitaliy Khutoryanskiy and Mun, {Grigoriy A.} and Khutoryanskiy, {Vitaliy V.} and Nurkeeva, {Zauresh S.} and Sergaziyev, {Aibek D.} and Fefelova, {Natalia A.} and Rosiak, {Janusz M.}",

year = "2004",

month = apr,

day = "15",

doi = "10.1002/polb.20051",

language = "English",

volume = "42",

pages = "1506--1513",

journal = "Journal of Polymer Science, Part B: Polymer Physics",

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Khutoryanskiy, V, Mun, GA, Khutoryanskiy, VV, Nurkeeva, ZS, Sergaziyev, AD, Fefelova, NA & Rosiak, JM 2004, 'Polyelectrolyte Complexes of Linear Copolymers and Hydrogels Based on 2-[(Methacryloyloxy)ethyl]trimethylammonium Chloride and N-Isopropylacrylamide', Journal of Polymer Science, Part B: Polymer Physics, vol. 42, no. 8, pp. 1506-1513. https://doi.org/10.1002/polb.20051

Polyelectrolyte Complexes of Linear Copolymers and Hydrogels Based on 2-[(Methacryloyloxy)ethyl]trimethylammonium Chloride and N-Isopropylacrylamide. / Khutoryanskiy, Vitaliy; Mun, Grigoriy A.; Khutoryanskiy, Vitaliy V. et al.
In: Journal of Polymer Science, Part B: Polymer Physics, Vol. 42, No. 8, 15.04.2004, p. 1506-1513.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Polyelectrolyte Complexes of Linear Copolymers and Hydrogels Based on 2-[(Methacryloyloxy)ethyl]trimethylammonium Chloride and N-Isopropylacrylamide

AU - Khutoryanskiy, Vitaliy

AU - Mun, Grigoriy A.

AU - Khutoryanskiy, Vitaliy V.

AU - Nurkeeva, Zauresh S.

AU - Sergaziyev, Aibek D.

AU - Fefelova, Natalia A.

AU - Rosiak, Janusz M.

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N2 - The formation of polyelectrolyte complexes of linear copolymers and hydrogels based on copolymers of 2-[(methacryloyloxy)ethyl]trimethylammonium chloride with N-isopropylacrylamide (MADQUAT-NIPAAM) and poly(acrylic acid) (PAA) has been studied. The composition of the copolymer has been found to affect the composition of the polyelectrolyte complexes significantly, and the molecular weight of PAA influences their aggregation stability. Hydrogels of MADQUAT-NIPAAM immersed in solutions of PAA undergo contraction because of the formation of gel-polymer complexes. The rate of contraction and the final swelling degree of the gel-polymer complexes depend on the concentration of PAA in solution and its molecular weight. © 2004 Wiley Periodicals, Inc.

AB - The formation of polyelectrolyte complexes of linear copolymers and hydrogels based on copolymers of 2-[(methacryloyloxy)ethyl]trimethylammonium chloride with N-isopropylacrylamide (MADQUAT-NIPAAM) and poly(acrylic acid) (PAA) has been studied. The composition of the copolymer has been found to affect the composition of the polyelectrolyte complexes significantly, and the molecular weight of PAA influences their aggregation stability. Hydrogels of MADQUAT-NIPAAM immersed in solutions of PAA undergo contraction because of the formation of gel-polymer complexes. The rate of contraction and the final swelling degree of the gel-polymer complexes depend on the concentration of PAA in solution and its molecular weight. © 2004 Wiley Periodicals, Inc.

KW - Hydrogels

KW - Poly(acrylic acid)

KW - Polyelectrolyte complexes

KW - Quaternary ammonium groups

KW - Swelling

KW - Water-soluble polymers

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DO - 10.1002/polb.20051

M3 - Article

SN - 0887-6266

VL - 42

SP - 1506

EP - 1513

JO - Journal of Polymer Science, Part B: Polymer Physics

JF - Journal of Polymer Science, Part B: Polymer Physics

IS - 8

ER -

Polyelectrolyte Complexes of Linear Copolymers and Hydrogels Based on 2-[(Methacryloyloxy)ethyl]trimethylammonium Chloride and N-Isopropylacrylamide

Abstract

Keywords

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