Polymerisation of a Cu(II) dimer into 1D chains using high pressure

Stephen A. Moggach; Kyle W. Galloway; Alistair R. Lennie; Pascal Parois; Niall Rowantree; Euan K. Brechin; John E. Warren; Mark Murrie; Simon Parsons

doi:10.1039/b912707k

Polymerisation of a Cu(II) dimer into 1D chains using high pressure

Stephen A. Moggach, Kyle W. Galloway, Alistair R. Lennie, Pascal Parois, Niall Rowantree, Euan K. Brechin, John E. Warren, Mark Murrie, Simon Parsons

Research output: Contribution to journal › Article › peer-review

Abstract

Long intermolecular interactions are converted into covalent bonds when the complex [Cu2(OH)(citrate)(Guanidine)2]- is exposed to a pressure of 2.9 GPa; the coordination of the Cu centres changes from [4 + 1] to [4 + 2], but on increasing the pressure to 4.2 GPa some of the Cu centres become [4 + 1]-coordinate again. © The Royal Society of Chemistry 2009.

Original language	English
Pages (from-to)	2601-2604
Number of pages	3
Journal	CrystEngComm
Volume	11
Issue number	12
DOIs	https://doi.org/10.1039/b912707k
Publication status	Published - 2009

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10.1039/b912707k

CCDC 731440: Experimental Crystal Structure Determination
Moggach, S. A. (Contributor), Galloway, K. W. (Contributor), Lennie, A. R. (Contributor), Parois, P. (Contributor), Rowantree, N. (Contributor), Brechin, E. K. (Contributor), Warren, J. (Contributor), Murrie, M. (Contributor) & Parsons, S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2010
DOI: 10.5517/ccsk3v8, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccsk3v8&sid=DataCite
Dataset
CCDC 731442: Experimental Crystal Structure Determination
Moggach, S. A. (Contributor), Galloway, K. W. (Contributor), Lennie, A. R. (Contributor), Parois, P. (Contributor), Rowantree, N. (Contributor), Brechin, E. K. (Contributor), Warren, J. (Contributor), Murrie, M. (Contributor) & Parsons, S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2010
DOI: 10.5517/ccsk3xb, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccsk3xb&sid=DataCite
Dataset
CCDC 731439: Experimental Crystal Structure Determination
Moggach, S. A. (Contributor), Galloway, K. W. (Contributor), Lennie, A. R. (Contributor), Parois, P. (Contributor), Rowantree, N. (Contributor), Brechin, E. K. (Contributor), Warren, J. (Contributor), Murrie, M. (Contributor) & Parsons, S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2010
DOI: 10.5517/ccsk3t7, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccsk3t7&sid=DataCite
Dataset

Cite this

@article{dd6375f5670b4968815e9d37bb82c41a,

title = "Polymerisation of a Cu(II) dimer into 1D chains using high pressure",

abstract = "Long intermolecular interactions are converted into covalent bonds when the complex [Cu2(OH)(citrate)(Guanidine)2]- is exposed to a pressure of 2.9 GPa; the coordination of the Cu centres changes from [4 + 1] to [4 + 2], but on increasing the pressure to 4.2 GPa some of the Cu centres become [4 + 1]-coordinate again. {\textcopyright} The Royal Society of Chemistry 2009.",

author = "Moggach, {Stephen A.} and Galloway, {Kyle W.} and Lennie, {Alistair R.} and Pascal Parois and Niall Rowantree and Brechin, {Euan K.} and Warren, {John E.} and Mark Murrie and Simon Parsons",

note = "12",

year = "2009",

doi = "10.1039/b912707k",

language = "English",

volume = "11",

pages = "2601--2604",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "12",

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TY - JOUR

T1 - Polymerisation of a Cu(II) dimer into 1D chains using high pressure

AU - Moggach, Stephen A.

AU - Galloway, Kyle W.

AU - Lennie, Alistair R.

AU - Parois, Pascal

AU - Rowantree, Niall

AU - Brechin, Euan K.

AU - Warren, John E.

AU - Murrie, Mark

AU - Parsons, Simon

N1 - 12

PY - 2009

Y1 - 2009

N2 - Long intermolecular interactions are converted into covalent bonds when the complex [Cu2(OH)(citrate)(Guanidine)2]- is exposed to a pressure of 2.9 GPa; the coordination of the Cu centres changes from [4 + 1] to [4 + 2], but on increasing the pressure to 4.2 GPa some of the Cu centres become [4 + 1]-coordinate again. © The Royal Society of Chemistry 2009.

AB - Long intermolecular interactions are converted into covalent bonds when the complex [Cu2(OH)(citrate)(Guanidine)2]- is exposed to a pressure of 2.9 GPa; the coordination of the Cu centres changes from [4 + 1] to [4 + 2], but on increasing the pressure to 4.2 GPa some of the Cu centres become [4 + 1]-coordinate again. © The Royal Society of Chemistry 2009.

U2 - 10.1039/b912707k

DO - 10.1039/b912707k

M3 - Article

SN - 1466-8033

VL - 11

SP - 2601

EP - 2604

JO - CrystEngComm

JF - CrystEngComm

IS - 12

ER -

Polymerisation of a Cu(II) dimer into 1D chains using high pressure

Abstract

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Datasets

CCDC 731440: Experimental Crystal Structure Determination

CCDC 731442: Experimental Crystal Structure Determination

CCDC 731439: Experimental Crystal Structure Determination

Cite this