@article{9593cdd6fc9341ffaf05674f81d50e63,
title = "Polymers of intrinsic microporosity derived from bis(phenazyl) monomers",
abstract = "Novel polymers of intrinsic microporosity (PIMs) are prepared from bis(phenazyl) monomers derived from readily available bis(catechol)s. One of the polymers (termed PIM-7) has an excellent combination of properties with high internal surface area, good film-forming characteristics, and gas transport properties that make it a suitable candidate for gas separation membranes. The high gas permeability and good ideal selectivity of PIM-7 place it above Robeson's upper-bound for a number of commercially important gas pairs (e.g., O2/N2, CO2/CH4, and CO 2/N2). {\textcopyright} 2008 American Chemical Society.",
keywords = "Cardo polymers, Ladder polymers Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (ladder polymers of intrinsic microporosity derived from bis(phenazyl) monomers), Porosity (microporosity, of ladder polymers of intrinsic microporosity derived from bis(phenazyl) monomers), Permeability, Surface area, Thermal stability (of ladder polymers of intrinsic microporosity derived from bis(phenazyl) monomers), Gases (transport properties, ladder polymers of intrinsic microporosity derived from bis(phenazyl) monomers), phenazyl catechol monomer ladder cardo polymer microporosity",
author = "Ghanem, {Bader S.} and McKeown, {Neil B.} and Budd, {Peter M.} and Detlev Fritsch",
note = "CAN 148:380045 35-5 Chemistry of Synthetic High Polymers School of Chemistry,Cardiff University,Cardiff,UK. Journal 120-80-9 (Catechol) Role: RCT (Reactant), RACT (Reactant or reagent) (in model compd. prepn.; ladder polymers of intrinsic microporosity derived from bis(phenazyl) monomers); 5348-42-5 (4,5-Dichlorobenzene-1,2-diamine) Role: RCT (Reactant), RACT (Reactant or reagent) (in monomer prepn.; ladder polymers of intrinsic microporosity derived from bis(phenazyl) monomers); 38475-60-4P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (in monomer prepn.; ladder polymers of intrinsic microporosity derived from bis(phenazyl) monomers); 839716-91-5P; 839716-92-6P; 839717-01-0P; 839717-02-1P; 1013632-56-8P; 1013632-58-0P; 1013632-60-4P; 1013632-62-6P; 1013632-64-8P; 1013632-65-9P; 1013632-66-0P; 1013632-67-1P Role: PRP (Properties), SPN (Synthetic preparation), PREP (Preparation) (ladder polymers of intrinsic microporosity derived from bis(phenazyl) monomers); 1013632-55-7P Role: SPN (Synthetic preparation), PREP (Preparation) (model compd.; ladder polymers of intrinsic microporosity derived from bis(phenazyl) monomers); 77-08-7; 95156-77-7; 351521-78-3 Role: RCT (Reactant), RACT (Reactant or reagent) (monomer; ladder polymers of intrinsic microporosity derived from bis(phenazyl) monomers); 839716-90-4P; 1013632-54-6P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (monomer; ladder polymers of intrinsic microporosity derived from bis(phenazyl) monomers); 74-82-8 (Methane); 124-38-9 (Carbon dioxide); 1333-74-0 (Hydrogen); 7440-37-1 (Argon); 7440-59-7 (Helium); 7440-63-3 (Xenon); 7727-37-9 (Nitrogen); 7782-44-7 (Oxygen) Role: PEP (Physical, engineering or chemical process), PRP (Properties), PROC (Process) (transport properties; ladder polymers of intrinsic microporosity derived from bis(phenazyl) monomers)",
year = "2008",
month = mar,
day = "11",
doi = "10.1021/ma071846r",
language = "English",
volume = "41",
pages = "1640--1646",
journal = "Macromolecules",
issn = "0024-9297",
publisher = "American Chemical Society",
number = "5",
}