Polynuclear cyanoruthenate chromophores based on hexaaza-triphenylene containing up to twelve cyanides: Photophysical and structural properties

Juan Manuel Herrera; Michael D. Ward; Harry Adams; S. J A Pope; Stephen Faulkner

doi:10.1039/b601876a

Polynuclear cyanoruthenate chromophores based on hexaaza-triphenylene containing up to twelve cyanides: Photophysical and structural properties

Juan Manuel Herrera, Michael D. Ward, Harry Adams, S. J A Pope, Stephen Faulkner

Research output: Contribution to journal › Article › peer-review

Abstract

The complexes [Ru(CN)4(HAT)]2-, [{Ru(CN) 4}2(μ2-HAT)]4- and [{Ru(CN) 4}3(μ3-HAT)]6- (HAT = hexaaza-triphenylene) contain four, eight and twelve externally-directed cyanide ligands, respectively; they show strongly solvatochromic and intense MLCT absorptions, and [3]6- forms a high-dimensionality cyanide-bridged coordination network with Nd(iii), in which Ru → Nd energy transfer results in sensitised near-IR luminescence. © The Royal Society of Chemistry 2006.

Original language	English
Pages (from-to)	1851-1853
Number of pages	2
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/b601876a
Publication status	Published - 2006

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10.1039/b601876a

CCDC 297959: Experimental Crystal Structure Determination
Herrera, J. M. (Contributor), Ward, M. D. (Contributor), Adams, H. (Contributor), Pope, S. J. A. (Contributor) & Faulkner, S. (Contributor), Cambridge Crystallographic Data Centre, 2006
DOI: 10.5517/ccb01ly, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccb01ly&sid=DataCite
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@article{7e10a539053d4e92a4998b59206ac194,

title = "Polynuclear cyanoruthenate chromophores based on hexaaza-triphenylene containing up to twelve cyanides: Photophysical and structural properties",

abstract = "The complexes [Ru(CN)4(HAT)]2-, [{Ru(CN) 4}2(μ2-HAT)]4- and [{Ru(CN) 4}3(μ3-HAT)]6- (HAT = hexaaza-triphenylene) contain four, eight and twelve externally-directed cyanide ligands, respectively; they show strongly solvatochromic and intense MLCT absorptions, and [3]6- forms a high-dimensionality cyanide-bridged coordination network with Nd(iii), in which Ru → Nd energy transfer results in sensitised near-IR luminescence. {\textcopyright} The Royal Society of Chemistry 2006.",

author = "Herrera, {Juan Manuel} and Ward, {Michael D.} and Harry Adams and Pope, {S. J A} and Stephen Faulkner",

year = "2006",

doi = "10.1039/b601876a",

language = "English",

pages = "1851--1853",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "17",

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TY - JOUR

T1 - Polynuclear cyanoruthenate chromophores based on hexaaza-triphenylene containing up to twelve cyanides: Photophysical and structural properties

AU - Herrera, Juan Manuel

AU - Ward, Michael D.

AU - Adams, Harry

AU - Pope, S. J A

AU - Faulkner, Stephen

PY - 2006

Y1 - 2006

N2 - The complexes [Ru(CN)4(HAT)]2-, [{Ru(CN) 4}2(μ2-HAT)]4- and [{Ru(CN) 4}3(μ3-HAT)]6- (HAT = hexaaza-triphenylene) contain four, eight and twelve externally-directed cyanide ligands, respectively; they show strongly solvatochromic and intense MLCT absorptions, and [3]6- forms a high-dimensionality cyanide-bridged coordination network with Nd(iii), in which Ru → Nd energy transfer results in sensitised near-IR luminescence. © The Royal Society of Chemistry 2006.

AB - The complexes [Ru(CN)4(HAT)]2-, [{Ru(CN) 4}2(μ2-HAT)]4- and [{Ru(CN) 4}3(μ3-HAT)]6- (HAT = hexaaza-triphenylene) contain four, eight and twelve externally-directed cyanide ligands, respectively; they show strongly solvatochromic and intense MLCT absorptions, and [3]6- forms a high-dimensionality cyanide-bridged coordination network with Nd(iii), in which Ru → Nd energy transfer results in sensitised near-IR luminescence. © The Royal Society of Chemistry 2006.

U2 - 10.1039/b601876a

DO - 10.1039/b601876a

M3 - Article

SN - 1359-7345

SP - 1851

EP - 1853

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Polynuclear cyanoruthenate chromophores based on hexaaza-triphenylene containing up to twelve cyanides: Photophysical and structural properties

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CCDC 297959: Experimental Crystal Structure Determination

Cite this