Probing the anions mediated associative behavior of tin-12 oxo-macrocations by pulsed field gradient NMR spectroscopy

Luk Van Lokeren; Rudolph Willem; David Van Der Beek; Patrick Davidson; Gareth A. Morris; François Ribot

doi:10.1021/jp100709j

Probing the anions mediated associative behavior of tin-12 oxo-macrocations by pulsed field gradient NMR spectroscopy

Luk Van Lokeren
, Rudolph Willem
, David Van Der Beek
, Patrick Davidson
, Gareth A. Morris
, François Ribot

Research output: Contribution to journal › Article › peer-review

Abstract

1H PFG NMR spectroscopy has been used to evidence the association of ditopic {(BuSn)12O14(OH)6} 2+ macrocations when sulfate or oxalate divalent anions are used to balance their positive charges. The existence of supramolecular species, the size of which can reach up to about 10 times the size of the individual building blocks, is clearly related to electrostatic interactions as the supramolecular species fully break down to their individual components in solvent with high dielectric constant. © 2010 American Chemical Society.

Original language	English
Pages (from-to)	16087-16091
Number of pages	4
Journal	Journal of Physical Chemistry C
Volume	114
Issue number	39
DOIs	https://doi.org/10.1021/jp100709j
Publication status	Published - 7 Oct 2010

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title = "Probing the anions mediated associative behavior of tin-12 oxo-macrocations by pulsed field gradient NMR spectroscopy",

abstract = "1H PFG NMR spectroscopy has been used to evidence the association of ditopic \{(BuSn)12O14(OH)6\} 2+ macrocations when sulfate or oxalate divalent anions are used to balance their positive charges. The existence of supramolecular species, the size of which can reach up to about 10 times the size of the individual building blocks, is clearly related to electrostatic interactions as the supramolecular species fully break down to their individual components in solvent with high dielectric constant. {\textcopyright} 2010 American Chemical Society.",

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doi = "10.1021/jp100709j",

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AU - Van Lokeren, Luk

AU - Willem, Rudolph

AU - Van Der Beek, David

AU - Davidson, Patrick

AU - Morris, Gareth A.

AU - Ribot, François

PY - 2010/10/7

Y1 - 2010/10/7

N2 - 1H PFG NMR spectroscopy has been used to evidence the association of ditopic {(BuSn)12O14(OH)6} 2+ macrocations when sulfate or oxalate divalent anions are used to balance their positive charges. The existence of supramolecular species, the size of which can reach up to about 10 times the size of the individual building blocks, is clearly related to electrostatic interactions as the supramolecular species fully break down to their individual components in solvent with high dielectric constant. © 2010 American Chemical Society.

AB - 1H PFG NMR spectroscopy has been used to evidence the association of ditopic {(BuSn)12O14(OH)6} 2+ macrocations when sulfate or oxalate divalent anions are used to balance their positive charges. The existence of supramolecular species, the size of which can reach up to about 10 times the size of the individual building blocks, is clearly related to electrostatic interactions as the supramolecular species fully break down to their individual components in solvent with high dielectric constant. © 2010 American Chemical Society.

U2 - 10.1021/jp100709j

DO - 10.1021/jp100709j

M3 - Article

SN - 1932-7447

VL - 114

SP - 16087

EP - 16091

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

IS - 39

ER -

Probing the anions mediated associative behavior of tin-12 oxo-macrocations by pulsed field gradient NMR spectroscopy

Abstract

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