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Abstract
A combination of the temperature- and pressure-dependencies of the kinetic isotope effect on the proton coupled electron transfer during ascorbate oxidation by ferricyanide suggests that this reference reaction may exploit vibrationally assisted quantum tunnelling of the transferred proton. © 2014 the Owner Societies.
Original language | English |
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Pages (from-to) | 2256-2259 |
Number of pages | 3 |
Journal | Physical Chemistry Chemical Physics |
Volume | 16 |
Issue number | 6 |
DOIs | |
Publication status | Published - 14 Feb 2014 |
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Dive into the research topics of 'Proton tunnelling and promoting vibrations during the oxidation of ascorbate by ferricyanide?'. Together they form a unique fingerprint.Projects
- 1 Finished
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Linking experiment to theory: Quantum entanglement during enzyme catalysis - Dr S Hay fellowship
Hay, S. (PI)
1/09/10 → 31/08/15
Project: Research