Protonation of Cp∗Fe(η5-C<inf>6</inf>H<inf>7</inf>) as a convenient procedure for the preparation of the valuable synthon [Cp∗Fe(MeCN)<inf>3</inf>]+

A.S. Romanov; M.M. Vinogradov; D.V. Muratov; A.R. Kudinov

doi:10.1016/j.mencom.2014.11.016

Protonation of Cp∗Fe(η5-C<inf>6</inf>H<inf>7</inf>) as a convenient procedure for the preparation of the valuable synthon [Cp∗Fe(MeCN)<inf>3</inf>]+

A.S. Romanov, M.M. Vinogradov, D.V. Muratov, A.R. Kudinov

Materials Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The (cyclohexadienyl)iron complex Cp*Fe(η5-C6H7) obtained by a reaction of the cation [Cp*Fe(η6-C6H6)]+ with LiAlH4 reacts with HBF4·Et2O or TfOH in MeCN to afford the acetonitrile cation [Cp*Fe(MeCN)3]+ in a high yield. The structure of complex Cp*Fe(η5-C6H7) was determined by X-ray diffraction analysis.

Original language	English
Pages (from-to)	358-359
Number of pages	2
Journal	Mendeleev Communications
Volume	24
Issue number	6
DOIs	https://doi.org/10.1016/j.mencom.2014.11.016
Publication status	Published - 2014

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title = "Protonation of Cp∗Fe(η5-C6H7) as a convenient procedure for the preparation of the valuable synthon [Cp∗Fe(MeCN)3]+",

abstract = "The (cyclohexadienyl)iron complex Cp*Fe(η5-C6H7) obtained by a reaction of the cation [Cp*Fe(η6-C6H6)]+ with LiAlH4 reacts with HBF4·Et2O or TfOH in MeCN to afford the acetonitrile cation [Cp*Fe(MeCN)3]+ in a high yield. The structure of complex Cp*Fe(η5-C6H7) was determined by X-ray diffraction analysis.",

author = "A.S. Romanov and M.M. Vinogradov and D.V. Muratov and A.R. Kudinov",

year = "2014",

doi = "10.1016/j.mencom.2014.11.016",

language = "English",

volume = "24",

pages = "358--359",

journal = "Mendeleev Communications",

issn = "0959-9436",

publisher = "Elsevier BV",

number = "6",

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TY - JOUR

T1 - Protonation of Cp∗Fe(η5-C6H7) as a convenient procedure for the preparation of the valuable synthon [Cp∗Fe(MeCN)3]+

AU - Romanov, A.S.

AU - Vinogradov, M.M.

AU - Muratov, D.V.

AU - Kudinov, A.R.

PY - 2014

Y1 - 2014

N2 - The (cyclohexadienyl)iron complex Cp*Fe(η5-C6H7) obtained by a reaction of the cation [Cp*Fe(η6-C6H6)]+ with LiAlH4 reacts with HBF4·Et2O or TfOH in MeCN to afford the acetonitrile cation [Cp*Fe(MeCN)3]+ in a high yield. The structure of complex Cp*Fe(η5-C6H7) was determined by X-ray diffraction analysis.

AB - The (cyclohexadienyl)iron complex Cp*Fe(η5-C6H7) obtained by a reaction of the cation [Cp*Fe(η6-C6H6)]+ with LiAlH4 reacts with HBF4·Et2O or TfOH in MeCN to afford the acetonitrile cation [Cp*Fe(MeCN)3]+ in a high yield. The structure of complex Cp*Fe(η5-C6H7) was determined by X-ray diffraction analysis.

UR - http://www.scopus.com/inward/record.url?eid=2-s2.0-84911917483&partnerID=MN8TOARS

U2 - 10.1016/j.mencom.2014.11.016

DO - 10.1016/j.mencom.2014.11.016

M3 - Article

SN - 0959-9436

VL - 24

SP - 358

EP - 359

JO - Mendeleev Communications

JF - Mendeleev Communications

IS - 6

ER -

Protonation of Cp∗Fe(η<sup>5</sup>-C<inf>6</inf>H<inf>7</inf>) as a convenient procedure for the preparation of the valuable synthon [Cp∗Fe(MeCN)<inf>3</inf>]<sup>+</sup>

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