[PtMe(iPr3P)2]+: A Pt(II) complex with an agostic interaction that undergoes C-H activation

Michael J. Ingleson, Mary F. Mahon, Andrew S. Weller

    Research output: Contribution to journalArticlepeer-review

    Abstract

    The T-shaped Pt(II) complex [PtMe(iPr3P) 2][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)(iPr 3P)(iPr2PCHMeCH2)][1-H-closo-CB 11Me11].
    Original languageEnglish
    Pages (from-to)2398-2399
    Number of pages1
    JournalChemical Communications
    Volume10
    Issue number21
    DOIs
    Publication statusPublished - 7 Nov 2004

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