Radial tetra(ferrocenyl)- and tetra(cymantrenyl)cyclobutadienecobalt complexes: Synthesis and structures

A.S. Romanov; T.V. Timofeeva; M.Y. Antipin

doi:10.1016/j.jorganchem.2011.08.014

Radial tetra(ferrocenyl)- and tetra(cymantrenyl)cyclobutadienecobalt complexes: Synthesis and structures

A.S. Romanov, T.V. Timofeeva, M.Y. Antipin

Materials Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Novel radial tetra(ferrocenyl)- and tetra(cymantrenyl)cyclobutadienecobalt complexes were prepared by metal carbonyls free protocol of [2 + 2] cycloaddition reaction of 1,2-diferrocenyl- or 1,2-dicymantrenylethynes with chlorotris(triphenylphospine)cobalt(I) and carboethoxycyclopentadienide sodium with good yields. The molecular structure of these products was confirmed with X-ray analysis, and their electrochemical behavior was studied.

Original language	English
Pages (from-to)	3822-3825
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	696
Issue number	23
DOIs	https://doi.org/10.1016/j.jorganchem.2011.08.014
Publication status	Published - Nov 2011

Keywords

Sandwich complexes
Electrochemistry
Cobalt
Ferrocene
Cymantrene

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10.1016/j.jorganchem.2011.08.014

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title = "Radial tetra(ferrocenyl)- and tetra(cymantrenyl)cyclobutadienecobalt complexes: Synthesis and structures",

abstract = "Novel radial tetra(ferrocenyl)- and tetra(cymantrenyl)cyclobutadienecobalt complexes were prepared by metal carbonyls free protocol of [2 + 2] cycloaddition reaction of 1,2-diferrocenyl- or 1,2-dicymantrenylethynes with chlorotris(triphenylphospine)cobalt(I) and carboethoxycyclopentadienide sodium with good yields. The molecular structure of these products was confirmed with X-ray analysis, and their electrochemical behavior was studied.",

keywords = "Sandwich complexes, Electrochemistry, Cobalt, Ferrocene, Cymantrene",

author = "A.S. Romanov and T.V. Timofeeva and M.Y. Antipin",

year = "2011",

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doi = "10.1016/j.jorganchem.2011.08.014",

language = "English",

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T1 - Radial tetra(ferrocenyl)- and tetra(cymantrenyl)cyclobutadienecobalt complexes: Synthesis and structures

AU - Romanov, A.S.

AU - Timofeeva, T.V.

AU - Antipin, M.Y.

PY - 2011/11

Y1 - 2011/11

N2 - Novel radial tetra(ferrocenyl)- and tetra(cymantrenyl)cyclobutadienecobalt complexes were prepared by metal carbonyls free protocol of [2 + 2] cycloaddition reaction of 1,2-diferrocenyl- or 1,2-dicymantrenylethynes with chlorotris(triphenylphospine)cobalt(I) and carboethoxycyclopentadienide sodium with good yields. The molecular structure of these products was confirmed with X-ray analysis, and their electrochemical behavior was studied.

AB - Novel radial tetra(ferrocenyl)- and tetra(cymantrenyl)cyclobutadienecobalt complexes were prepared by metal carbonyls free protocol of [2 + 2] cycloaddition reaction of 1,2-diferrocenyl- or 1,2-dicymantrenylethynes with chlorotris(triphenylphospine)cobalt(I) and carboethoxycyclopentadienide sodium with good yields. The molecular structure of these products was confirmed with X-ray analysis, and their electrochemical behavior was studied.

KW - Sandwich complexes

KW - Electrochemistry

KW - Cobalt

KW - Ferrocene

KW - Cymantrene

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U2 - 10.1016/j.jorganchem.2011.08.014

DO - 10.1016/j.jorganchem.2011.08.014

M3 - Article

VL - 696

SP - 3822

EP - 3825

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 23

ER -

Radial tetra(ferrocenyl)- and tetra(cymantrenyl)cyclobutadienecobalt complexes: Synthesis and structures

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Keywords

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