Radiation grafting from binary monomer mixtures. I. Vinyl ether of monoethanolamine and vinyl ether of ethyleneglycol

Vitaliy Khutoryanskiy; Zauresh S. Nurkeeva; Al Sayed Abdel Aal; Vitaliy V. Khutoryanskiy; Grigoriy A. Mun; Aida G. Beksyrgaeva

doi:10.1016/S0969-806X(03)00149-X

Radiation grafting from binary monomer mixtures. I. Vinyl ether of monoethanolamine and vinyl ether of ethyleneglycol

Vitaliy Khutoryanskiy, Zauresh S. Nurkeeva, Al Sayed Abdel Aal, Vitaliy V. Khutoryanskiy, Grigoriy A. Mun, Aida G. Beksyrgaeva

Research output: Contribution to journal › Article › peer-review

Abstract

Gamma-radiation grafting of vinyl ether of monoethanolamine and vinyl ether of ethyleneglycol (VEEG) on polyethylene films has been studied from binary monomer mixtures. The effect of co-monomer composition and total exposure radiation dose on the grafting process is investigated. A combination of potentiometric and gravimetric techniques is applied to determine the grafting degree of each monomer in the final graft copolymer. The presence of more active monomer VEEG in the mixture was found to enhance the grafting of both monomers because the increasing of copolymerization rate which in turn increases the total grafting degree. The modification of the hydrophilic properties of the graft copolymer is studied by examining the grafted films for water- and copper (II) ions uptake. © 2003 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	717-722
Number of pages	5
Journal	Radiation Physics and Chemistry
Volume	67
Issue number	6
DOIs	https://doi.org/10.1016/S0969-806X(03)00149-X
Publication status	Published - 1 Aug 2003

Keywords

Binary mixtures
Cationic polymer
Metal uptake
Radiation grafting
Vinyl ethers

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10.1016/S0969-806X(03)00149-X

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title = "Radiation grafting from binary monomer mixtures. I. Vinyl ether of monoethanolamine and vinyl ether of ethyleneglycol",

abstract = "Gamma-radiation grafting of vinyl ether of monoethanolamine and vinyl ether of ethyleneglycol (VEEG) on polyethylene films has been studied from binary monomer mixtures. The effect of co-monomer composition and total exposure radiation dose on the grafting process is investigated. A combination of potentiometric and gravimetric techniques is applied to determine the grafting degree of each monomer in the final graft copolymer. The presence of more active monomer VEEG in the mixture was found to enhance the grafting of both monomers because the increasing of copolymerization rate which in turn increases the total grafting degree. The modification of the hydrophilic properties of the graft copolymer is studied by examining the grafted films for water- and copper (II) ions uptake. {\textcopyright} 2003 Elsevier Science Ltd. All rights reserved.",

keywords = "Binary mixtures, Cationic polymer, Metal uptake, Radiation grafting, Vinyl ethers",

author = "Vitaliy Khutoryanskiy and Nurkeeva, {Zauresh S.} and {Abdel Aal}, {Al Sayed} and Khutoryanskiy, {Vitaliy V.} and Mun, {Grigoriy A.} and Beksyrgaeva, {Aida G.}",

year = "2003",

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doi = "10.1016/S0969-806X(03)00149-X",

language = "English",

volume = "67",

pages = "717--722",

journal = "Radiation Physics and Chemistry",

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TY - JOUR

T1 - Radiation grafting from binary monomer mixtures. I. Vinyl ether of monoethanolamine and vinyl ether of ethyleneglycol

AU - Khutoryanskiy, Vitaliy

AU - Nurkeeva, Zauresh S.

AU - Abdel Aal, Al Sayed

AU - Khutoryanskiy, Vitaliy V.

AU - Mun, Grigoriy A.

AU - Beksyrgaeva, Aida G.

PY - 2003/8/1

Y1 - 2003/8/1

N2 - Gamma-radiation grafting of vinyl ether of monoethanolamine and vinyl ether of ethyleneglycol (VEEG) on polyethylene films has been studied from binary monomer mixtures. The effect of co-monomer composition and total exposure radiation dose on the grafting process is investigated. A combination of potentiometric and gravimetric techniques is applied to determine the grafting degree of each monomer in the final graft copolymer. The presence of more active monomer VEEG in the mixture was found to enhance the grafting of both monomers because the increasing of copolymerization rate which in turn increases the total grafting degree. The modification of the hydrophilic properties of the graft copolymer is studied by examining the grafted films for water- and copper (II) ions uptake. © 2003 Elsevier Science Ltd. All rights reserved.

AB - Gamma-radiation grafting of vinyl ether of monoethanolamine and vinyl ether of ethyleneglycol (VEEG) on polyethylene films has been studied from binary monomer mixtures. The effect of co-monomer composition and total exposure radiation dose on the grafting process is investigated. A combination of potentiometric and gravimetric techniques is applied to determine the grafting degree of each monomer in the final graft copolymer. The presence of more active monomer VEEG in the mixture was found to enhance the grafting of both monomers because the increasing of copolymerization rate which in turn increases the total grafting degree. The modification of the hydrophilic properties of the graft copolymer is studied by examining the grafted films for water- and copper (II) ions uptake. © 2003 Elsevier Science Ltd. All rights reserved.

KW - Binary mixtures

KW - Cationic polymer

KW - Metal uptake

KW - Radiation grafting

KW - Vinyl ethers

U2 - 10.1016/S0969-806X(03)00149-X

DO - 10.1016/S0969-806X(03)00149-X

M3 - Article

SN - 1879-0895

VL - 67

SP - 717

EP - 722

JO - Radiation Physics and Chemistry

JF - Radiation Physics and Chemistry

IS - 6

ER -

Radiation grafting from binary monomer mixtures. I. Vinyl ether of monoethanolamine and vinyl ether of ethyleneglycol

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Keywords

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