Radiation synthesis of polyampholyte hydrogels based on vinyl ether of monoethanolamine and sodium acrylate and their interactions with linear polyelectrolytes

Vitaliy Khutoryanskiy; Grigoriy A. Mun; Zauresh S. Nurkeeva; Sabit M. Koblanov; Vitaliy V. Khutoryanskiy; Erengaip M. Shaikhutdinov

doi:10.1016/j.radphyschem.2003.11.002

Radiation synthesis of polyampholyte hydrogels based on vinyl ether of monoethanolamine and sodium acrylate and their interactions with linear polyelectrolytes

Vitaliy Khutoryanskiy, Grigoriy A. Mun, Zauresh S. Nurkeeva, Sabit M. Koblanov, Vitaliy V. Khutoryanskiy, Erengaip M. Shaikhutdinov

Research output: Contribution to journal › Article › peer-review

Abstract

Polyampholyte hydrogels were synthesized by gamma-radiation-induced copolymerization of vinyl ether of monoethanolamine with sodium acrylate. The synthesis regularities of the hydrogels have been studied. The effects of the feed mixture, cross-linker concentration, absorbed dose on the gel/sol fractions and swelling behavior of the hydrogels is studied. The swelling behavior of the hydrogels was studied as a function of pH. It was found that the isoelectric point of the polyampholyte hydrogels depends on the composition of copolymers. The interactions of the synthesized hydrogels with linear poly(acrylic acid) and poly(vinyl ether of monoethanolamine) lead to the formation of gel-polymer interpolyelectrolyte complexes. © 2003 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	1031-1037
Number of pages	6
Journal	Radiation Physics and Chemistry
Volume	71
Issue number	5
DOIs	https://doi.org/10.1016/j.radphyschem.2003.11.002
Publication status	Published - Dec 2004

Keywords

Hydrogels
Polyampholytes
Polyelectrolyte complexes
Vinyl ethers

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10.1016/j.radphyschem.2003.11.002

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Khutoryanskiy, V., Mun, G. A., Nurkeeva, Z. S., Koblanov, S. M., Khutoryanskiy, V. V., & Shaikhutdinov, E. M. (2004). Radiation synthesis of polyampholyte hydrogels based on vinyl ether of monoethanolamine and sodium acrylate and their interactions with linear polyelectrolytes. Radiation Physics and Chemistry, 71(5), 1031-1037. https://doi.org/10.1016/j.radphyschem.2003.11.002

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title = "Radiation synthesis of polyampholyte hydrogels based on vinyl ether of monoethanolamine and sodium acrylate and their interactions with linear polyelectrolytes",

abstract = "Polyampholyte hydrogels were synthesized by gamma-radiation-induced copolymerization of vinyl ether of monoethanolamine with sodium acrylate. The synthesis regularities of the hydrogels have been studied. The effects of the feed mixture, cross-linker concentration, absorbed dose on the gel/sol fractions and swelling behavior of the hydrogels is studied. The swelling behavior of the hydrogels was studied as a function of pH. It was found that the isoelectric point of the polyampholyte hydrogels depends on the composition of copolymers. The interactions of the synthesized hydrogels with linear poly(acrylic acid) and poly(vinyl ether of monoethanolamine) lead to the formation of gel-polymer interpolyelectrolyte complexes. {\textcopyright} 2003 Elsevier Ltd. All rights reserved.",

keywords = "Hydrogels, Polyampholytes, Polyelectrolyte complexes, Vinyl ethers",

author = "Vitaliy Khutoryanskiy and Mun, {Grigoriy A.} and Nurkeeva, {Zauresh S.} and Koblanov, {Sabit M.} and Khutoryanskiy, {Vitaliy V.} and Shaikhutdinov, {Erengaip M.}",

year = "2004",

month = dec,

doi = "10.1016/j.radphyschem.2003.11.002",

language = "English",

volume = "71",

pages = "1031--1037",

journal = "Radiation Physics and Chemistry",

issn = "1879-0895",

publisher = "Elsevier BV",

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Khutoryanskiy, V, Mun, GA, Nurkeeva, ZS, Koblanov, SM, Khutoryanskiy, VV & Shaikhutdinov, EM 2004, 'Radiation synthesis of polyampholyte hydrogels based on vinyl ether of monoethanolamine and sodium acrylate and their interactions with linear polyelectrolytes', Radiation Physics and Chemistry, vol. 71, no. 5, pp. 1031-1037. https://doi.org/10.1016/j.radphyschem.2003.11.002

Radiation synthesis of polyampholyte hydrogels based on vinyl ether of monoethanolamine and sodium acrylate and their interactions with linear polyelectrolytes. / Khutoryanskiy, Vitaliy; Mun, Grigoriy A.; Nurkeeva, Zauresh S. et al.
In: Radiation Physics and Chemistry, Vol. 71, No. 5, 12.2004, p. 1031-1037.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Radiation synthesis of polyampholyte hydrogels based on vinyl ether of monoethanolamine and sodium acrylate and their interactions with linear polyelectrolytes

AU - Khutoryanskiy, Vitaliy

AU - Mun, Grigoriy A.

AU - Nurkeeva, Zauresh S.

AU - Koblanov, Sabit M.

AU - Khutoryanskiy, Vitaliy V.

AU - Shaikhutdinov, Erengaip M.

PY - 2004/12

Y1 - 2004/12

N2 - Polyampholyte hydrogels were synthesized by gamma-radiation-induced copolymerization of vinyl ether of monoethanolamine with sodium acrylate. The synthesis regularities of the hydrogels have been studied. The effects of the feed mixture, cross-linker concentration, absorbed dose on the gel/sol fractions and swelling behavior of the hydrogels is studied. The swelling behavior of the hydrogels was studied as a function of pH. It was found that the isoelectric point of the polyampholyte hydrogels depends on the composition of copolymers. The interactions of the synthesized hydrogels with linear poly(acrylic acid) and poly(vinyl ether of monoethanolamine) lead to the formation of gel-polymer interpolyelectrolyte complexes. © 2003 Elsevier Ltd. All rights reserved.

AB - Polyampholyte hydrogels were synthesized by gamma-radiation-induced copolymerization of vinyl ether of monoethanolamine with sodium acrylate. The synthesis regularities of the hydrogels have been studied. The effects of the feed mixture, cross-linker concentration, absorbed dose on the gel/sol fractions and swelling behavior of the hydrogels is studied. The swelling behavior of the hydrogels was studied as a function of pH. It was found that the isoelectric point of the polyampholyte hydrogels depends on the composition of copolymers. The interactions of the synthesized hydrogels with linear poly(acrylic acid) and poly(vinyl ether of monoethanolamine) lead to the formation of gel-polymer interpolyelectrolyte complexes. © 2003 Elsevier Ltd. All rights reserved.

KW - Hydrogels

KW - Polyampholytes

KW - Polyelectrolyte complexes

KW - Vinyl ethers

U2 - 10.1016/j.radphyschem.2003.11.002

DO - 10.1016/j.radphyschem.2003.11.002

M3 - Article

SN - 1879-0895

VL - 71

SP - 1031

EP - 1037

JO - Radiation Physics and Chemistry

JF - Radiation Physics and Chemistry

IS - 5

ER -

Radiation synthesis of polyampholyte hydrogels based on vinyl ether of monoethanolamine and sodium acrylate and their interactions with linear polyelectrolytes

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Keywords

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