Raman spectrum of graphene and graphene layers

A. C. Ferrari, J. C. Meyer, V. Scardaci, C. Casiraghi, M. Lazzeri, F. Mauri, S. Piscanec, D. Jiang, K. S. Novoselov, S. Roth, A. K. Geim

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Graphene is the two-dimensional building block for carbon allotropes of every other dimensionality. We show that its electronic structure is captured in its Raman spectrum that clearly evolves with the number of layers. The D peak second order changes in shape, width, and position for an increasing number of layers, reflecting the change in the electron bands via a double resonant Raman process. The G peak slightly down-shifts. This allows unambiguous, high-throughput, nondestructive identification of graphene layers, which is critically lacking in this emerging research area. © 2006 The American Physical Society.
    Original languageEnglish
    Article number187401
    JournalPhysical Review Letters
    Volume97
    Issue number18
    DOIs
    Publication statusPublished - 2006

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