Raman spectrum of [Ru(CNBut)(CO)(η2-C 6-H4-2-CHO)(PPh3)2][BF 4]·2CDCl3 shows that the crystallographically determined bifurcated hydrogen-bonding interaction Cl3CD⋯ F2BF2- is an example of a blue-shifting hydrogen bond

Alan K. Brisdon; Kevin R. Flower; Robin G. Pritchard

doi:10.1021/ic701065w

Raman spectrum of [Ru(CNBut)(CO)(η2-C 6-H4-2-CHO)(PPh3)2][BF 4]·2CDCl3 shows that the crystallographically determined bifurcated hydrogen-bonding interaction Cl3CD⋯ F2BF2- is an example of a blue-shifting hydrogen bond

Alan K. Brisdon, Kevin R. Flower, Robin G. Pritchard

Research output: Contribution to journal › Article › peer-review

Abstract

Raman data suggest that a crystallographically determined Cl 3CD⋯F2BF2- interaction in the solid-state structure of [Ru(CNBut)(CO)(η2-C 6-H4-2-CHO)(PPh3)2][BF 4]·2CDCl3 is an example of a blue-shifting bifurcated hydrogen bond. The ν(C-D) band blue-shifts 5 cm-1 to 2269 cm-1 compared to 2264 cm-1 for CDCl3 in the gas phase and 20 cm-1 from frozen CDCl3 at 2249 cm-1. A conventional interpretation of these band shifts would suggest that the CCl2 fragment of DCCl3 is a stronger hydrogen-bond acceptor than the BF2 fragment of a BF4 - group. © 2007 American Chemical Society.

Original language	English
Pages (from-to)	7189-7192
Number of pages	3
Journal	Inorganic Chemistry: including bioinorganic chemistry
Volume	46
Issue number	17
DOIs	https://doi.org/10.1021/ic701065w
Publication status	Published - 20 Aug 2007

Access to Document

10.1021/ic701065w

Fingerprint

Dive into the research topics of 'Raman spectrum of [Ru(CNBut)(CO)(η2-C 6-H4-2-CHO)(PPh3)2][BF 4]·2CDCl3 shows that the crystallographically determined bifurcated hydrogen-bonding interaction Cl3CD⋯ F2BF2- is an example of a blue-shifting hydrogen bond'. Together they form a unique fingerprint.

CCDC 637474: Experimental Crystal Structure Determination
Brisdon, A. (Contributor), Flower, K. R. (Contributor) & Pritchard, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2008
DOI: 10.5517/ccpdbp2, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccpdbp2&sid=DataCite
Dataset

Cite this

Brisdon, A. K., Flower, K. R., & Pritchard, R. G. (2007). Raman spectrum of [Ru(CNBut)(CO)(η2-C 6-H4-2-CHO)(PPh3)2][BF 4]·2CDCl3 shows that the crystallographically determined bifurcated hydrogen-bonding interaction Cl3CD⋯ F2BF2- is an example of a blue-shifting hydrogen bond. Inorganic Chemistry: including bioinorganic chemistry , 46(17), 7189-7192. https://doi.org/10.1021/ic701065w

Brisdon, Alan K. ; Flower, Kevin R. ; Pritchard, Robin G. / Raman spectrum of [Ru(CNBut)(CO)(η2-C 6-H4-2-CHO)(PPh3)2][BF 4]·2CDCl3 shows that the crystallographically determined bifurcated hydrogen-bonding interaction Cl3CD⋯ F2BF2- is an example of a blue-shifting hydrogen bond. In: Inorganic Chemistry: including bioinorganic chemistry . 2007 ; Vol. 46, No. 17. pp. 7189-7192.

@article{16dd901cc4dd45bdb421247311e27899,

title = "Raman spectrum of [Ru(CNBut)(CO)(η2-C 6-H4-2-CHO)(PPh3)2][BF 4]·2CDCl3 shows that the crystallographically determined bifurcated hydrogen-bonding interaction Cl3CD⋯ F2BF2- is an example of a blue-shifting hydrogen bond",

abstract = "Raman data suggest that a crystallographically determined Cl 3CD⋯F2BF2- interaction in the solid-state structure of [Ru(CNBut)(CO)(η2-C 6-H4-2-CHO)(PPh3)2][BF 4]·2CDCl3 is an example of a blue-shifting bifurcated hydrogen bond. The ν(C-D) band blue-shifts 5 cm-1 to 2269 cm-1 compared to 2264 cm-1 for CDCl3 in the gas phase and 20 cm-1 from frozen CDCl3 at 2249 cm-1. A conventional interpretation of these band shifts would suggest that the CCl2 fragment of DCCl3 is a stronger hydrogen-bond acceptor than the BF2 fragment of a BF4 - group. {\textcopyright} 2007 American Chemical Society.",

author = "Brisdon, {Alan K.} and Flower, {Kevin R.} and Pritchard, {Robin G.}",

note = "Times Cited: 1",

year = "2007",

month = aug,

day = "20",

doi = "10.1021/ic701065w",

language = "English",

volume = "46",

pages = "7189--7192",

journal = "Inorganic Chemistry: including bioinorganic chemistry ",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "17",

}

Brisdon, AK, Flower, KR & Pritchard, RG 2007, 'Raman spectrum of [Ru(CNBut)(CO)(η2-C 6-H4-2-CHO)(PPh3)2][BF 4]·2CDCl3 shows that the crystallographically determined bifurcated hydrogen-bonding interaction Cl3CD⋯ F2BF2- is an example of a blue-shifting hydrogen bond', Inorganic Chemistry: including bioinorganic chemistry , vol. 46, no. 17, pp. 7189-7192. https://doi.org/10.1021/ic701065w

Raman spectrum of [Ru(CNBut)(CO)(η2-C 6-H4-2-CHO)(PPh3)2][BF 4]·2CDCl3 shows that the crystallographically determined bifurcated hydrogen-bonding interaction Cl3CD⋯ F2BF2- is an example of a blue-shifting hydrogen bond. / Brisdon, Alan K.; Flower, Kevin R.; Pritchard, Robin G.
In: Inorganic Chemistry: including bioinorganic chemistry , Vol. 46, No. 17, 20.08.2007, p. 7189-7192.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Raman spectrum of [Ru(CNBut)(CO)(η2-C 6-H4-2-CHO)(PPh3)2][BF 4]·2CDCl3 shows that the crystallographically determined bifurcated hydrogen-bonding interaction Cl3CD⋯ F2BF2- is an example of a blue-shifting hydrogen bond

AU - Brisdon, Alan K.

AU - Flower, Kevin R.

AU - Pritchard, Robin G.

N1 - Times Cited: 1

PY - 2007/8/20

Y1 - 2007/8/20

N2 - Raman data suggest that a crystallographically determined Cl 3CD⋯F2BF2- interaction in the solid-state structure of [Ru(CNBut)(CO)(η2-C 6-H4-2-CHO)(PPh3)2][BF 4]·2CDCl3 is an example of a blue-shifting bifurcated hydrogen bond. The ν(C-D) band blue-shifts 5 cm-1 to 2269 cm-1 compared to 2264 cm-1 for CDCl3 in the gas phase and 20 cm-1 from frozen CDCl3 at 2249 cm-1. A conventional interpretation of these band shifts would suggest that the CCl2 fragment of DCCl3 is a stronger hydrogen-bond acceptor than the BF2 fragment of a BF4 - group. © 2007 American Chemical Society.

AB - Raman data suggest that a crystallographically determined Cl 3CD⋯F2BF2- interaction in the solid-state structure of [Ru(CNBut)(CO)(η2-C 6-H4-2-CHO)(PPh3)2][BF 4]·2CDCl3 is an example of a blue-shifting bifurcated hydrogen bond. The ν(C-D) band blue-shifts 5 cm-1 to 2269 cm-1 compared to 2264 cm-1 for CDCl3 in the gas phase and 20 cm-1 from frozen CDCl3 at 2249 cm-1. A conventional interpretation of these band shifts would suggest that the CCl2 fragment of DCCl3 is a stronger hydrogen-bond acceptor than the BF2 fragment of a BF4 - group. © 2007 American Chemical Society.

U2 - 10.1021/ic701065w

DO - 10.1021/ic701065w

M3 - Article

SN - 0020-1669

VL - 46

SP - 7189

EP - 7192

JO - Inorganic Chemistry: including bioinorganic chemistry

JF - Inorganic Chemistry: including bioinorganic chemistry

IS - 17

ER -

Raman spectrum of [Ru(CNBut)(CO)(η2-C 6-H4-2-CHO)(PPh3)2][BF 4]·2CDCl3 shows that the crystallographically determined bifurcated hydrogen-bonding interaction Cl3CD⋯ F2BF2- is an example of a blue-shifting hydrogen bond

Abstract

Access to Document

Fingerprint

Datasets

CCDC 637474: Experimental Crystal Structure Determination

Cite this