Abstract
A predictable stereoselective method for the synthesis of enantiopure anti, anti-1,2,3-triols through the addition of organometallic reagents to the axially disposed aldehyde derived from (R′,R′,S,R)-2,3-butane diacetal protected butanetetraol is described.
| Original language | English |
|---|---|
| Pages (from-to) | 2516-2518 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society. Perkin Transactions 1 |
| Issue number | 20 |
| DOIs | |
| Publication status | Published - 2001 |
Keywords
- Addition reaction; Asymmetric synthesis and induction (rapid assembly of anti,anti-1,2,3-triol motifs via stereoselective addn. of organometallics to aldehydes obtained from (R',R',S,R)-2,3-butane diacetal protected butanetetraol derivs.); Alcohols Role: PNU (Preparation, unclassified), PREP (Preparation) (trihydric, 1,2,3-; rapid assembly of anti,anti-1,2,3-triol motifs via stereoselective addn. of organometallics to aldehydes obtained from (R',R',S,R)-2,3-butane diacetal protected butanetetraol derivs.)