Reactions of Cp₂M (M = Ni, V) with dilithium diamido-aryl reagents; retention and oxidation of the transition metal ions

Francesca A. Stokes; Mark A. Vincent; Ian H. Hillier; Tanya K. Ronson; Alexander Steiner; Andrew E. H. Wheatley; Paul T. Wood; Dominic S. Wright

doi:10.1039/c3dt51632f

Reactions of Cp₂M (M = Ni, V) with dilithium diamido-aryl reagents; retention and oxidation of the transition metal ions

Francesca A. Stokes, Mark A. Vincent, Ian H. Hillier, Tanya K. Ronson, Alexander Steiner, Andrew E. H. Wheatley, Paul T. Wood, Dominic S. Wright

Research output: Contribution to journal › Article › peer-review

Abstract

The reactions of dilithium 1,2-diamidobenzene, [1,2-(HN)2C6H4]Li2 (L1111H2222)Li2, and dilithium 1,8-diamidonaphthalene, [1,8-(NH)2C10H6]Li2 (L222H222)Li2, with Cp2Ni and Cp2V have been used to obtain the new complexes (L222H222)2Ni{Li(THF)2}2 (3), (L222H222)3V{Li(THF)2}3 (4) and (L1111H2222)6Ni6·{[(L1111H2222)3(L11H)3Ni6Li(THF)]2−·2[Li(THF)4]+} (5), in which retention or oxidation of the initial metal(II) centre is observed. Whereas 3 and 4 contain one transition metal ion within ion-paired structures, 5 has a complicated co-crystalline composition which contains octahedral Ni6-cages constructed from six square-planar (16e) NiII centres.

Original language	English
Pages (from-to)	13923
Journal	Dalton Transactions
Volume	42
Issue number	38
DOIs	https://doi.org/10.1039/c3dt51632f
Publication status	Published - 1 Jan 2013

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CCDC 943108: Experimental Crystal Structure Determination
Stokes, F. A. (Creator), Vincent, M. (Creator), Hillier, I. (Creator), Ronson, T. K. (Creator), Steiner, A. (Creator), Wheatley, A. E. H. (Creator), Wood, P. T. (Creator) & Wright, D. S. (Creator), Cambridge Crystallographic Data Centre, 6 Jun 2013
DOI: 10.5517/cc10ncvw
Dataset
CCDC 943106: Experimental Crystal Structure Determination
Stokes, F. A. (Creator), Vincent, M. (Creator), Hillier, I. (Creator), Ronson, T. K. (Creator), Steiner, A. (Creator), Wheatley, A. E. H. (Creator), Wood, P. T. (Creator) & Wright, D. S. (Creator), Cambridge Crystallographic Data Centre, 6 Jun 2013
DOI: 10.5517/cc10ncst
Dataset
CCDC 943107: Experimental Crystal Structure Determination
Stokes, F. A. (Creator), Vincent, M. (Creator), Hillier, I. (Creator), Ronson, T. K. (Creator), Steiner, A. (Creator), Wheatley, A. E. H. (Creator), Wood, P. T. (Creator) & Wright, D. S. (Creator), Cambridge Crystallographic Data Centre, 6 Jun 2013
DOI: 10.5517/cc10nctv
Dataset

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@article{c150fde4e6e94101847e68b640e03d30,

title = "Reactions of Cp₂M (M = Ni, V) with dilithium diamido-aryl reagents; retention and oxidation of the transition metal ions",

abstract = "The reactions of dilithium 1,2-diamidobenzene, [1,2-(HN)2C6H4]Li2 (L1111H2222)Li2, and dilithium 1,8-diamidonaphthalene, [1,8-(NH)2C10H6]Li2 (L222H222)Li2, with Cp2Ni and Cp2V have been used to obtain the new complexes (L222H222)2Ni{Li(THF)2}2 (3), (L222H222)3V{Li(THF)2}3 (4) and (L1111H2222)6Ni6·{[(L1111H2222)3(L11H)3Ni6Li(THF)]2−·2[Li(THF)4]+} (5), in which retention or oxidation of the initial metal(II) centre is observed. Whereas 3 and 4 contain one transition metal ion within ion-paired structures, 5 has a complicated co-crystalline composition which contains octahedral Ni6-cages constructed from six square-planar (16e) NiII centres.",

author = "Stokes, {Francesca A.} and Vincent, {Mark A.} and Hillier, {Ian H.} and Ronson, {Tanya K.} and Alexander Steiner and Wheatley, {Andrew E. H.} and Wood, {Paul T.} and Wright, {Dominic S.}",

year = "2013",

month = jan,

day = "1",

doi = "10.1039/c3dt51632f",

language = "English",

volume = "42",

pages = "13923",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

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}

TY - JOUR

T1 - Reactions of Cp₂M (M = Ni, V) with dilithium diamido-aryl reagents; retention and oxidation of the transition metal ions

AU - Stokes, Francesca A.

AU - Vincent, Mark A.

AU - Hillier, Ian H.

AU - Ronson, Tanya K.

AU - Steiner, Alexander

AU - Wheatley, Andrew E. H.

AU - Wood, Paul T.

AU - Wright, Dominic S.

PY - 2013/1/1

Y1 - 2013/1/1

N2 - The reactions of dilithium 1,2-diamidobenzene, [1,2-(HN)2C6H4]Li2 (L1111H2222)Li2, and dilithium 1,8-diamidonaphthalene, [1,8-(NH)2C10H6]Li2 (L222H222)Li2, with Cp2Ni and Cp2V have been used to obtain the new complexes (L222H222)2Ni{Li(THF)2}2 (3), (L222H222)3V{Li(THF)2}3 (4) and (L1111H2222)6Ni6·{[(L1111H2222)3(L11H)3Ni6Li(THF)]2−·2[Li(THF)4]+} (5), in which retention or oxidation of the initial metal(II) centre is observed. Whereas 3 and 4 contain one transition metal ion within ion-paired structures, 5 has a complicated co-crystalline composition which contains octahedral Ni6-cages constructed from six square-planar (16e) NiII centres.

AB - The reactions of dilithium 1,2-diamidobenzene, [1,2-(HN)2C6H4]Li2 (L1111H2222)Li2, and dilithium 1,8-diamidonaphthalene, [1,8-(NH)2C10H6]Li2 (L222H222)Li2, with Cp2Ni and Cp2V have been used to obtain the new complexes (L222H222)2Ni{Li(THF)2}2 (3), (L222H222)3V{Li(THF)2}3 (4) and (L1111H2222)6Ni6·{[(L1111H2222)3(L11H)3Ni6Li(THF)]2−·2[Li(THF)4]+} (5), in which retention or oxidation of the initial metal(II) centre is observed. Whereas 3 and 4 contain one transition metal ion within ion-paired structures, 5 has a complicated co-crystalline composition which contains octahedral Ni6-cages constructed from six square-planar (16e) NiII centres.

U2 - 10.1039/c3dt51632f

DO - 10.1039/c3dt51632f

M3 - Article

VL - 42

SP - 13923

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 38

ER -

Reactions of Cp₂M (M = Ni, V) with dilithium diamido-aryl reagents; retention and oxidation of the transition metal ions

Abstract

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Datasets

CCDC 943108: Experimental Crystal Structure Determination

CCDC 943106: Experimental Crystal Structure Determination

CCDC 943107: Experimental Crystal Structure Determination

Cite this