Abstract
The three-coordinate iron(ii) NHC complexes [(IPr)Fe(N′′) 2] (1) and [(ItBu)Fe(N′′)2] (3) (N′′ = N(SiMe3)2) react with PhSeH or LiSePh to give the iron(ii) selenolates [(IPr)Fe(N′′)(SePh)] (6) and [ItBu(H)][(aItBu)Fe(SePh)3], [I tBu(H)][7], with complex 7 containing an abnormal NHC ligand. © 2014 The Royal Society of Chemistry.
| Original language | English |
|---|---|
| Pages (from-to) | 4251-4254 |
| Number of pages | 3 |
| Journal | Dalton Transactions |
| Volume | 43 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - 21 Mar 2014 |
Fingerprint
Dive into the research topics of 'Reactivity of three-coordinate iron-NHC complexes towards phenylselenol and lithium phenylselenide'. Together they form a unique fingerprint.Datasets
-
CCDC 971589: Experimental Crystal Structure Determination
Pugh, T. (Contributor) & Layfield, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/cc11m0l8, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc11m0l8&sid=DataCite
Dataset
-
CCDC 971588: Experimental Crystal Structure Determination
Pugh, T. (Contributor) & Layfield, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/cc11m0k7, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc11m0k7&sid=DataCite
Dataset
-
CCDC 971590: Experimental Crystal Structure Determination
Pugh, T. (Contributor) & Layfield, R. (Contributor), Cambridge Crystallographic Data Centre, 12 Nov 2013
DOI: 10.5517/cc11m0m9, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc11m0m9&sid=DataCite
Dataset