Redox-controlled crotyl alcohol selective oxidation: In situ oxidation and reduction dynamics of catalytic Pd nanoparticles via synchronous XANES/MS

Christine V. Gaskell; Christopher M.A. Parlett; Mark A. Newton; Karen Wilson; Adam F. Lee

doi:10.1021/cs300445y

Redox-controlled crotyl alcohol selective oxidation: In situ oxidation and reduction dynamics of catalytic Pd nanoparticles via synchronous XANES/MS

Christine V. Gaskell, Christopher M.A. Parlett, Mark A. Newton, Karen Wilson, Adam F. Lee

Research output: Contribution to journal › Article › peer-review

Abstract

In-situ, synchronous MS/XANES reveals the Pd catalyzed selective aerobic oxidation of crotyl alcohol is regulated by the balance between the oxidation state and reducibility. Dynamic XANES measurements provide a new, rapid method to determine redox kinetics of nanoparticles and identify important parameters to optimize catalyst design.

Original language	English
Pages (from-to)	2242-2246
Number of pages	5
Journal	ACS Catalysis
Volume	2
Issue number	11
DOIs	https://doi.org/10.1021/cs300445y
Publication status	Published - 2 Nov 2012

Keywords

alcohol
kinetics
palladium
selective oxidation
XAS

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10.1021/cs300445y

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title = "Redox-controlled crotyl alcohol selective oxidation: In situ oxidation and reduction dynamics of catalytic Pd nanoparticles via synchronous XANES/MS",

abstract = "In-situ, synchronous MS/XANES reveals the Pd catalyzed selective aerobic oxidation of crotyl alcohol is regulated by the balance between the oxidation state and reducibility. Dynamic XANES measurements provide a new, rapid method to determine redox kinetics of nanoparticles and identify important parameters to optimize catalyst design.",

keywords = "alcohol, kinetics, palladium, selective oxidation, XAS",

author = "Gaskell, {Christine V.} and Parlett, {Christopher M.A.} and Newton, {Mark A.} and Karen Wilson and Lee, {Adam F.}",

year = "2012",

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journal = "ACS Catalysis",

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T2 - In situ oxidation and reduction dynamics of catalytic Pd nanoparticles via synchronous XANES/MS

AU - Gaskell, Christine V.

AU - Parlett, Christopher M.A.

AU - Newton, Mark A.

AU - Wilson, Karen

AU - Lee, Adam F.

PY - 2012/11/2

Y1 - 2012/11/2

N2 - In-situ, synchronous MS/XANES reveals the Pd catalyzed selective aerobic oxidation of crotyl alcohol is regulated by the balance between the oxidation state and reducibility. Dynamic XANES measurements provide a new, rapid method to determine redox kinetics of nanoparticles and identify important parameters to optimize catalyst design.

AB - In-situ, synchronous MS/XANES reveals the Pd catalyzed selective aerobic oxidation of crotyl alcohol is regulated by the balance between the oxidation state and reducibility. Dynamic XANES measurements provide a new, rapid method to determine redox kinetics of nanoparticles and identify important parameters to optimize catalyst design.

KW - alcohol

KW - kinetics

KW - palladium

KW - selective oxidation

KW - XAS

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DO - 10.1021/cs300445y

M3 - Article

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SN - 2155-5435

VL - 2

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JO - ACS Catalysis

JF - ACS Catalysis

IS - 11

ER -

Redox-controlled crotyl alcohol selective oxidation: In situ oxidation and reduction dynamics of catalytic Pd nanoparticles via synchronous XANES/MS

Abstract

Keywords

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