TY - JOUR
T1 - Redox-state dependent spectroscopic properties of porous organic polymers containing furan, thiophene, and selenophene
AU - Hua, Carol
AU - Woo, Stone
AU - Rawal, Aditya
AU - Tuna, Floriana
AU - Hook, James M.
AU - Collison, David
AU - D'Alessandro, Deanna M.
PY - 2017
Y1 - 2017
N2 - A series of electroactive triarylamine porous organic polymers (POPs) with furan, thiophene, and selenophene (POP-O, POP-S, and POP-Se) linkers have been synthesised and their electronic and spectroscopic properties investigated as a function of redox state. Solid state NMR provided insight into the structural features of the POPs, while in situ solid state Vis-NIR and electron paramagnetic resonance spectroelectrochemistry showed that the distinct redox states in POP-S could be reversibly accessed. The development of redox-active porous organic polymers with heterocyclic linkers affords their potential application as stimuli responsive materials in gas storage, catalysis, and as electrochromic materials.
AB - A series of electroactive triarylamine porous organic polymers (POPs) with furan, thiophene, and selenophene (POP-O, POP-S, and POP-Se) linkers have been synthesised and their electronic and spectroscopic properties investigated as a function of redox state. Solid state NMR provided insight into the structural features of the POPs, while in situ solid state Vis-NIR and electron paramagnetic resonance spectroelectrochemistry showed that the distinct redox states in POP-S could be reversibly accessed. The development of redox-active porous organic polymers with heterocyclic linkers affords their potential application as stimuli responsive materials in gas storage, catalysis, and as electrochromic materials.
UR - http://www.scopus.com/inward/record.url?scp=85032662332&partnerID=8YFLogxK
U2 - 10.1071/CH17335
DO - 10.1071/CH17335
M3 - Article
AN - SCOPUS:85032662332
SN - 0004-9425
VL - 70
SP - 1227
EP - 1234
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 11
ER -