Reduction of α-aryloxy carbonyl compounds with samarium(II) iodide. A new traceless linker for the solid phase synthesis of carbonyl compounds

Fiona McKerlie, David J. Procter, Graham Wynne

    Research output: Contribution to journalArticlepeer-review

    Abstract

    A new linker for the solid phase synthesis of functionalised carbonyl compounds which is cleaved under mild, neutral conditions using samarium(II) iodide has been developed; the manipulation of an immobilised γ-butyrolactone has been carried out to illustrate the utility of the linker.
    Original languageEnglish
    Pages (from-to)584-585
    Number of pages1
    JournalChemical Communications
    Issue number6
    DOIs
    Publication statusPublished - 21 Mar 2002

    Keywords

    • Reduction; Solid phase synthesis (solid phase synthesis of carbonyl compds. by redn. of a-aryloxy carbonyl compds. with samarium(II) iodide); Carbonyl compounds Role: SPN (Synthetic preparation), PREP (Preparation) (solid phase synthesis of carbonyl compds. by redn. of a-aryloxy carbonyl compds. with samarium(II) iodide)

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