Reductive cyclization cascades of lactones using SmI2-H 2O

Dixit Parmar; Kieran Price; Malcolm Spain; Hiroshi Matsubara; Paul A. Bradley; David J. Procter

doi:10.1021/ja1114908

Reductive cyclization cascades of lactones using SmI2-H 2O

Dixit Parmar, Kieran Price, Malcolm Spain, Hiroshi Matsubara, Paul A. Bradley, David J. Procter

Research output: Contribution to journal › Article › peer-review

Abstract

Lactones bearing two alkenes or an alkene and an alkyne undergo reductive cyclization cascades upon treatment with SmI2-H2O, giving decorated azulene motifs in excellent yields with good diastereocontrol. © 2011 American Chemical Society.

Original language	English
Pages (from-to)	2418-2420
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	133
Issue number	8
DOIs	https://doi.org/10.1021/ja1114908
Publication status	Published - 2 Mar 2011

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10.1021/ja1114908

CCDC 804695: Experimental Crystal Structure Determination
Parmar, D. (Contributor), Price, K. (Contributor), Spain, M. (Contributor), Matsubara, H. (Contributor), Bradley, P. A. (Contributor) & Procter, D. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccw0bx3, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccw0bx3&sid=DataCite
Dataset
CCDC 804694: Experimental Crystal Structure Determination
Parmar, D. (Contributor), Price, K. (Contributor), Spain, M. (Contributor), Matsubara, H. (Contributor), Bradley, P. A. (Contributor) & Procter, D. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccw0bw2, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccw0bw2&sid=DataCite
Dataset
CCDC 804696: Experimental Crystal Structure Determination
Parmar, D. (Contributor), Price, K. (Contributor), Spain, M. (Contributor), Matsubara, H. (Contributor), Bradley, P. A. (Contributor) & Procter, D. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2011
DOI: 10.5517/ccw0by4, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccw0by4&sid=DataCite
Dataset

Cite this

@article{a4cc3cafe79b43dbbad66af6ccb550e5,

title = "Reductive cyclization cascades of lactones using SmI2-H 2O",

abstract = "Lactones bearing two alkenes or an alkene and an alkyne undergo reductive cyclization cascades upon treatment with SmI2-H2O, giving decorated azulene motifs in excellent yields with good diastereocontrol. {\textcopyright} 2011 American Chemical Society.",

author = "Dixit Parmar and Kieran Price and Malcolm Spain and Hiroshi Matsubara and Bradley, {Paul A.} and Procter, {David J.}",

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AU - Parmar, Dixit

AU - Price, Kieran

AU - Spain, Malcolm

AU - Matsubara, Hiroshi

AU - Bradley, Paul A.

AU - Procter, David J.

PY - 2011/3/2

Y1 - 2011/3/2

N2 - Lactones bearing two alkenes or an alkene and an alkyne undergo reductive cyclization cascades upon treatment with SmI2-H2O, giving decorated azulene motifs in excellent yields with good diastereocontrol. © 2011 American Chemical Society.

AB - Lactones bearing two alkenes or an alkene and an alkyne undergo reductive cyclization cascades upon treatment with SmI2-H2O, giving decorated azulene motifs in excellent yields with good diastereocontrol. © 2011 American Chemical Society.

U2 - 10.1021/ja1114908

DO - 10.1021/ja1114908

M3 - Article

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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Reductive cyclization cascades of lactones using SmI2-H 2O

Abstract

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Datasets

CCDC 804695: Experimental Crystal Structure Determination

CCDC 804694: Experimental Crystal Structure Determination

CCDC 804696: Experimental Crystal Structure Determination

Cite this