Removal of naphthenic acids from crude oil using amino acid ionic liquids

K. Anderson, P. Goodrich, C. Hardacre, A. Hussain, D. W. Rooney, D. Wassell

    Research output: Contribution to journalArticlepeer-review

    Abstract

    (Chemical Equation Presented) A number of tetraalkylammonium and tetraalkylphosphonium amino acid based ionic liquids (AAILs) have been successfully used and recycled for the reactive extraction of naphthenic acids from crude oil and crude oil distillates. Spectral studies show that the mechanism by which this occurs is through the formation of a zwitterionic complex. Therein, the amino acid anion plays a key role in the formation of this complex.

    Original languageEnglish
    Pages (from-to)715-722
    Number of pages8
    JournalFuel
    Volume108
    DOIs
    Publication statusPublished - 2013

    Keywords

    • Amino acid
    • Extraction
    • Ionic liquid
    • Naphthenic acid
    • Neutralisation

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