Reverse-Keggin ions: Polycondensation of antimonate ligands give inorganic cryptand

Viswanathan Baskar; Maheswaran Shanmugam; Madeleine Helliwell; Simon J. Teat; Richard E P Winpenny

doi:10.1021/ja068214p

Reverse-Keggin ions: Polycondensation of antimonate ligands give inorganic cryptand

Viswanathan Baskar, Maheswaran Shanmugam, Madeleine Helliwell, Simon J. Teat, Richard E P Winpenny

Research output: Contribution to journal › Article › peer-review

Abstract

Reverse-Keggin ions are reported in which a p-block element (antimony) occupies the twelve vertices of a truncated tetrahedron while a d-block element (manganese or zinc) occupies the tetrahedral central cavity. The exterior of the reverse-Keggins also acts as tridentate ligands to further d-block centers. Copyright © 2007 American Chemical Society.

Original language	English
Pages (from-to)	3042-3043
Number of pages	1
Journal	Journal of the American Chemical Society
Volume	129
Issue number	11
DOIs	https://doi.org/10.1021/ja068214p
Publication status	Published - 21 Mar 2007

Keywords

COMPLEXES
ALUMINUM

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10.1021/ja068214p

http://rylibweb.man.ac.uk/cgi-bin/acsa.pl?jacsat

CCDC 645108: Experimental Crystal Structure Determination
Baskar, V. (Contributor), Shanmugam, M. (Contributor), Helliwell, M. (Contributor), Teat, S. J. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2007
DOI: 10.5517/ccpn8yj, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccpn8yj&sid=DataCite
Dataset
CCDC 645111: Experimental Crystal Structure Determination
Baskar, V. (Contributor), Shanmugam, M. (Contributor), Helliwell, M. (Contributor), Teat, S. J. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2007
DOI: 10.5517/ccpn91n, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccpn91n&sid=DataCite
Dataset
CCDC 645109: Experimental Crystal Structure Determination
Baskar, V. (Contributor), Shanmugam, M. (Contributor), Helliwell, M. (Contributor), Teat, S. J. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2007
DOI: 10.5517/ccpn8zk, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccpn8zk&sid=DataCite
Dataset

Cite this

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title = "Reverse-Keggin ions: Polycondensation of antimonate ligands give inorganic cryptand",

abstract = "Reverse-Keggin ions are reported in which a p-block element (antimony) occupies the twelve vertices of a truncated tetrahedron while a d-block element (manganese or zinc) occupies the tetrahedral central cavity. The exterior of the reverse-Keggins also acts as tridentate ligands to further d-block centers. Copyright {\textcopyright} 2007 American Chemical Society.",

keywords = "COMPLEXES, ALUMINUM",

author = "Viswanathan Baskar and Maheswaran Shanmugam and Madeleine Helliwell and Teat, {Simon J.} and Winpenny, {Richard E P}",

note = "Baskar, Viswanathan Shanmugam, Maheswaran Helliwell, Madeleine Teat, Simon J. Winpenny, Richard E. P. 23 AMER CHEMICAL SOC WASHINGTON 145WQ",

year = "2007",

month = mar,

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doi = "10.1021/ja068214p",

language = "English",

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journal = "Journal of the American Chemical Society",

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T1 - Reverse-Keggin ions: Polycondensation of antimonate ligands give inorganic cryptand

AU - Baskar, Viswanathan

AU - Shanmugam, Maheswaran

AU - Helliwell, Madeleine

AU - Teat, Simon J.

AU - Winpenny, Richard E P

N1 - Baskar, Viswanathan Shanmugam, Maheswaran Helliwell, Madeleine Teat, Simon J. Winpenny, Richard E. P. 23 AMER CHEMICAL SOC WASHINGTON 145WQ

PY - 2007/3/21

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N2 - Reverse-Keggin ions are reported in which a p-block element (antimony) occupies the twelve vertices of a truncated tetrahedron while a d-block element (manganese or zinc) occupies the tetrahedral central cavity. The exterior of the reverse-Keggins also acts as tridentate ligands to further d-block centers. Copyright © 2007 American Chemical Society.

AB - Reverse-Keggin ions are reported in which a p-block element (antimony) occupies the twelve vertices of a truncated tetrahedron while a d-block element (manganese or zinc) occupies the tetrahedral central cavity. The exterior of the reverse-Keggins also acts as tridentate ligands to further d-block centers. Copyright © 2007 American Chemical Society.

KW - COMPLEXES

KW - ALUMINUM

U2 - 10.1021/ja068214p

DO - 10.1021/ja068214p

M3 - Article

SN - 0002-7863

VL - 129

SP - 3042

EP - 3043

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 11

ER -

Reverse-Keggin ions: Polycondensation of antimonate ligands give inorganic cryptand

Abstract

Keywords

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Datasets

CCDC 645108: Experimental Crystal Structure Determination

CCDC 645111: Experimental Crystal Structure Determination

CCDC 645109: Experimental Crystal Structure Determination

Cite this