Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer

Mark R. Warren, Simon K. Brayshaw, Andrew L. Johnson, Stefanie Schiffers, Paul R. Raithby, Timothy L. Easun, Michael W. George, John E. Warren, Simon J. Teat

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Nitrites of passage: Raman and single-crystal photocrystallographic studies on [Ni(dppe)( η1-NO2)Cl] have, for the first time, identified a system which undergoes a reversible 100 % conversion into the metastable isomer in the solid state, in this case the [Ni(dppe) (η1-ONO)Cl] isomer. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
    Original languageEnglish
    Pages (from-to)5711-5714
    Number of pages3
    JournalAngewandte Chemie - International Edition
    Volume48
    Issue number31
    DOIs
    Publication statusPublished - 20 Jul 2009

    Keywords

    • Linkage isomerism
    • Metastable compounds
    • Nitrites
    • Photocrystallography
    • Raman spectroscopy

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