Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer

Mark R. Warren; Simon K. Brayshaw; Andrew L. Johnson; Stefanie Schiffers; Paul R. Raithby; Timothy L. Easun; Michael W. George; John E. Warren; Simon J. Teat

doi:10.1002/anie.200901706

Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer

Mark R. Warren
, Simon K. Brayshaw
, Andrew L. Johnson
, Stefanie Schiffers
, Paul R. Raithby
, Timothy L. Easun
, Michael W. George
, John E. Warren
, Simon J. Teat

Research output: Contribution to journal › Article › peer-review

Abstract

Nitrites of passage: Raman and single-crystal photocrystallographic studies on [Ni(dppe)( η1-NO2)Cl] have, for the first time, identified a system which undergoes a reversible 100 % conversion into the metastable isomer in the solid state, in this case the [Ni(dppe) (η1-ONO)Cl] isomer. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	5711-5714
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	48
Issue number	31
DOIs	https://doi.org/10.1002/anie.200901706
Publication status	Published - 20 Jul 2009

Keywords

Linkage isomerism
Metastable compounds
Nitrites
Photocrystallography
Raman spectroscopy

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10.1002/anie.200901706

http://www3.interscience.wiley.com/cgi-bin/fulltext/122473522/PDFSTART

CCDC 724867: Experimental Crystal Structure Determination
Warren, M. R. (Contributor), Brayshaw, S. K. (Contributor), Johnson, A. L. (Contributor), Schiffers, S. (Contributor), Raithby, P. R. (Contributor), Easun, T. L. (Contributor), George, M. W. (Contributor), Warren, J. (Contributor) & Teat, S. J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2010
DOI: 10.5517/ccsb8t5, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccsb8t5&sid=DataCite
Dataset
CCDC 724868: Experimental Crystal Structure Determination
Warren, M. R. (Contributor), Brayshaw, S. K. (Contributor), Johnson, A. L. (Contributor), Schiffers, S. (Contributor), Raithby, P. R. (Contributor), Easun, T. L. (Contributor), George, M. W. (Contributor), Warren, J. (Contributor) & Teat, S. J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2010
DOI: 10.5517/ccsb8v6, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccsb8v6&sid=DataCite
Dataset
CCDC 724869: Experimental Crystal Structure Determination
Warren, M. R. (Contributor), Brayshaw, S. K. (Contributor), Johnson, A. L. (Contributor), Schiffers, S. (Contributor), Raithby, P. R. (Contributor), Easun, T. L. (Contributor), George, M. W. (Contributor), Warren, J. (Contributor) & Teat, S. J. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2010
DOI: 10.5517/ccsb8w7, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccsb8w7&sid=DataCite
Dataset

Cite this

Warren, M. R., Brayshaw, S. K., Johnson, A. L., Schiffers, S., Raithby, P. R., Easun, T. L., George, M. W., Warren, J. E., & Teat, S. J. (2009). Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer. Angewandte Chemie - International Edition, 48(31), 5711-5714. https://doi.org/10.1002/anie.200901706

@article{bfe4de0f5b464888960e744cb5e20c89,

title = "Reversible 100 \% linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer",

abstract = "Nitrites of passage: Raman and single-crystal photocrystallographic studies on [Ni(dppe)( η1-NO2)Cl] have, for the first time, identified a system which undergoes a reversible 100 \% conversion into the metastable isomer in the solid state, in this case the [Ni(dppe) (η1-ONO)Cl] isomer. {\textcopyright} 2009 Wiley-VCH Verlag GmbH \& Co. KGaA.",

keywords = "Linkage isomerism, Metastable compounds, Nitrites, Photocrystallography, Raman spectroscopy",

author = "Warren, \{Mark R.\} and Brayshaw, \{Simon K.\} and Johnson, \{Andrew L.\} and Stefanie Schiffers and Raithby, \{Paul R.\} and Easun, \{Timothy L.\} and George, \{Michael W.\} and Warren, \{John E.\} and Teat, \{Simon J.\}",

note = "31",

year = "2009",

month = jul,

day = "20",

doi = "10.1002/anie.200901706",

language = "English",

volume = "48",

pages = "5711--5714",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

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number = "31",

}

Warren, MR, Brayshaw, SK, Johnson, AL, Schiffers, S, Raithby, PR, Easun, TL, George, MW, Warren, JE & Teat, SJ 2009, 'Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer', Angewandte Chemie - International Edition, vol. 48, no. 31, pp. 5711-5714. https://doi.org/10.1002/anie.200901706

Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer. / Warren, Mark R.; Brayshaw, Simon K.; Johnson, Andrew L. et al.
In: Angewandte Chemie - International Edition, Vol. 48, No. 31, 20.07.2009, p. 5711-5714.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer

AU - Warren, Mark R.

AU - Brayshaw, Simon K.

AU - Johnson, Andrew L.

AU - Schiffers, Stefanie

AU - Raithby, Paul R.

AU - Easun, Timothy L.

AU - George, Michael W.

AU - Warren, John E.

AU - Teat, Simon J.

N1 - 31

PY - 2009/7/20

Y1 - 2009/7/20

N2 - Nitrites of passage: Raman and single-crystal photocrystallographic studies on [Ni(dppe)( η1-NO2)Cl] have, for the first time, identified a system which undergoes a reversible 100 % conversion into the metastable isomer in the solid state, in this case the [Ni(dppe) (η1-ONO)Cl] isomer. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - Nitrites of passage: Raman and single-crystal photocrystallographic studies on [Ni(dppe)( η1-NO2)Cl] have, for the first time, identified a system which undergoes a reversible 100 % conversion into the metastable isomer in the solid state, in this case the [Ni(dppe) (η1-ONO)Cl] isomer. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - Linkage isomerism

KW - Metastable compounds

KW - Nitrites

KW - Photocrystallography

KW - Raman spectroscopy

U2 - 10.1002/anie.200901706

DO - 10.1002/anie.200901706

M3 - Article

SN - 1433-7851

VL - 48

SP - 5711

EP - 5714

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 31

ER -

Reversible 100 % linkage isomerization in a single-crystal to single-crystal transformation: Photocrystallographic identification of the metastable [Ni(dppe)(η1-ONO)C1] isomer

Abstract

Keywords

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Datasets

CCDC 724867: Experimental Crystal Structure Determination

CCDC 724868: Experimental Crystal Structure Determination

CCDC 724869: Experimental Crystal Structure Determination

Cite this