Reversible C-C bond formation: Solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation

Lee Jon Ball, Anthony P. Dickie, Francis S. Mair, David A. Middleton, Robin G. Pritchard

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Analysis of crystals of the lithium complex of the tripodal ligand formed upon addition of adamantanone to a 1,5 diazapentadienyllithium complex reveals a long C-C bond which ruptures upon dissolution in non-co-ordinating solvents.
    Original languageEnglish
    Pages (from-to)744-745
    Number of pages1
    JournalChemical Communications
    Volume9
    Issue number6
    DOIs
    Publication statusPublished - 21 Mar 2003

    Fingerprint

    Dive into the research topics of 'Reversible C-C bond formation: Solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation'. Together they form a unique fingerprint.

    Cite this