Reversible C-C bond formation: Solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation

Lee Jon Ball; Anthony P. Dickie; Francis S. Mair; David A. Middleton; Robin G. Pritchard

doi:10.1039/b211745b

Reversible C-C bond formation: Solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation

Lee Jon Ball
, Anthony P. Dickie
, Francis S. Mair
, David A. Middleton
, Robin G. Pritchard

Research output: Contribution to journal › Article › peer-review

Abstract

Analysis of crystals of the lithium complex of the tripodal ligand formed upon addition of adamantanone to a 1,5 diazapentadienyllithium complex reveals a long C-C bond which ruptures upon dissolution in non-co-ordinating solvents.

Original language	English
Pages (from-to)	744-745
Number of pages	1
Journal	Chemical Communications
Volume	9
Issue number	6
DOIs	https://doi.org/10.1039/b211745b
Publication status	Published - 21 Mar 2003

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10.1039/b211745b

http://www.rsc.org/delivery/_ArticleLinking/DisplayArticleForFree.cfm?doi=b211745b&JournalCode=CC

CCDC 199213: Experimental Crystal Structure Determination
Ball, L. J. (Contributor), Dickie, A. P. (Contributor), Mair, F. (Contributor), Middleton, D. (Contributor) & Pritchard, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2003
DOI: 10.5517/cc6p97d, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc6p97d&sid=DataCite
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@article{0161da7d6baf44b2986ec70253639192,

title = "Reversible C-C bond formation: Solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation",

abstract = "Analysis of crystals of the lithium complex of the tripodal ligand formed upon addition of adamantanone to a 1,5 diazapentadienyllithium complex reveals a long C-C bond which ruptures upon dissolution in non-co-ordinating solvents.",

author = "Ball, \{Lee Jon\} and Dickie, \{Anthony P.\} and Mair, \{Francis S.\} and Middleton, \{David A.\} and Pritchard, \{Robin G.\}",

year = "2003",

month = mar,

day = "21",

doi = "10.1039/b211745b",

language = "English",

volume = "9",

pages = "744--745",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "6",

}

Reversible C-C bond formation: Solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation. / Ball, Lee Jon; Dickie, Anthony P.; Mair, Francis S. et al.
In: Chemical Communications, Vol. 9, No. 6, 21.03.2003, p. 744-745.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Reversible C-C bond formation: Solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation

AU - Ball, Lee Jon

AU - Dickie, Anthony P.

AU - Mair, Francis S.

AU - Middleton, David A.

AU - Pritchard, Robin G.

PY - 2003/3/21

Y1 - 2003/3/21

N2 - Analysis of crystals of the lithium complex of the tripodal ligand formed upon addition of adamantanone to a 1,5 diazapentadienyllithium complex reveals a long C-C bond which ruptures upon dissolution in non-co-ordinating solvents.

AB - Analysis of crystals of the lithium complex of the tripodal ligand formed upon addition of adamantanone to a 1,5 diazapentadienyllithium complex reveals a long C-C bond which ruptures upon dissolution in non-co-ordinating solvents.

U2 - 10.1039/b211745b

DO - 10.1039/b211745b

M3 - Article

C2 - 12703802

SN - 1359-7345

VL - 9

SP - 744

EP - 745

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Reversible C-C bond formation: Solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation

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CCDC 199213: Experimental Crystal Structure Determination

Cite this