TY - JOUR
T1 - Review of Polybed pressure swing adsorption for hydrogen purification
AU - Luberti, Mauro
AU - Ahn, Hyungwoong
N1 - Publisher Copyright:
© 2022 Hydrogen Energy Publications LLC
PY - 2022/3/5
Y1 - 2022/3/5
N2 - Hydrogen (H2) will play a key role in the future low-carbon energy society. The industrial production of hydrogen involves chemical reactions and purification steps. Pressure Swing Adsorption (PSA) is a versatile process able to produce ultrapure hydrogen (99.99+%) from various gas mixtures, resulting in the most widespread purification technology worldwide. In particular, the Polybed PSA system, having more than six beds and a complex cycle configuration, has proven to maximize H2 recovery and H2 throughput, exceeding 90% and 240 MMSCFD (265,000 Nm3 h−1) per single train, respectively. This paper systematically reviews the Polybed H2 PSA process for the first time, highlighting the latest technical advances and discussing its optimal integration in industrial clusters. A bespoke Polybed PSA process designed for simultaneous production of high-purity hydrogen and carbon dioxide (CO2) is also reviewed in light of the recent international directives aimed to reduce CO2 emissions and produce blue hydrogen.
AB - Hydrogen (H2) will play a key role in the future low-carbon energy society. The industrial production of hydrogen involves chemical reactions and purification steps. Pressure Swing Adsorption (PSA) is a versatile process able to produce ultrapure hydrogen (99.99+%) from various gas mixtures, resulting in the most widespread purification technology worldwide. In particular, the Polybed PSA system, having more than six beds and a complex cycle configuration, has proven to maximize H2 recovery and H2 throughput, exceeding 90% and 240 MMSCFD (265,000 Nm3 h−1) per single train, respectively. This paper systematically reviews the Polybed H2 PSA process for the first time, highlighting the latest technical advances and discussing its optimal integration in industrial clusters. A bespoke Polybed PSA process designed for simultaneous production of high-purity hydrogen and carbon dioxide (CO2) is also reviewed in light of the recent international directives aimed to reduce CO2 emissions and produce blue hydrogen.
KW - Blue hydrogen
KW - Carbon dioxide capture
KW - Cycle scheduling
KW - Hydrogen purification
KW - Layered bed
KW - Polybed pressure swing adsorption
UR - http://www.scopus.com/inward/record.url?scp=85124549680&partnerID=8YFLogxK
U2 - 10.1016/j.ijhydene.2022.01.147
DO - 10.1016/j.ijhydene.2022.01.147
M3 - Review article
AN - SCOPUS:85124549680
SN - 0360-3199
VL - 47
SP - 10911
EP - 10933
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
IS - 20
ER -