[Rh7(PiPr3)6H18][BAr F4]2: A molecular Rh(111) surface decorated with 18 hydrogen atoms

Simon K. Brayshaw; Jennifer C. Green; Ruth Edge; Eric J L McInnes; Paul R. Raithby; John E. Warren; Andrew S. Weller

doi:10.1002/anie.200703069

[Rh7(PiPr3)6H18][BAr F4]2: A molecular Rh(111) surface decorated with 18 hydrogen atoms

Simon K. Brayshaw, Jennifer C. Green, Ruth Edge, Eric J L McInnes, Paul R. Raithby, John E. Warren, Andrew S. Weller

Research output: Contribution to journal › Article › peer-review

Abstract

Heptarhodium wagon wheel [Rh7(PiPr3) 6H18][BArF4]2 (shown), which resembles a planar Rh(111) surface with 18 hydride ligands, was obtained together with [Rh8(PiPr3)6H16] [BArF4]2 from the reaction of [Rh(PiPr 3)2(nbd)][BArF4] and [Rh(nbd) 2][BArF4] with hydrogen (ArF = C6H3(CF3)2, nbd = norbornadiene). Some of the H ligands are located in threefold hollows between Rh centers and thus mimic the orientation of atomic hydrogen adsorbed on Rh(111). (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	7844-7848
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	41
DOIs	https://doi.org/10.1002/anie.200703069
Publication status	Published - 2007

Keywords

Cluster compounds
Density functional calculations
Hydride ligands
Hydrogen
Rhodium

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10.1002/anie.200703069

CCDC 652792: Experimental Crystal Structure Determination
Brayshaw, S. K. (Contributor), Green, J. C. (Contributor), Edge, R. (Contributor), Mcinnes, E. (Contributor), Raithby, P. R. (Contributor), Warren, J. (Contributor) & Weller, A. S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2008
DOI: 10.5517/ccpx8tn, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccpx8tn&sid=DataCite
Dataset
CCDC 652793: Experimental Crystal Structure Determination
Brayshaw, S. K. (Contributor), Green, J. C. (Contributor), Edge, R. (Contributor), Mcinnes, E. (Contributor), Raithby, P. R. (Contributor), Warren, J. (Contributor) & Weller, A. S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2008
DOI: 10.5517/ccpx8vp, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccpx8vp&sid=DataCite
Dataset

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@article{b3514862d01443feb805b0aed953c437,

title = "[Rh7(PiPr3)6H18][BAr F4]2: A molecular Rh(111) surface decorated with 18 hydrogen atoms",

abstract = "Heptarhodium wagon wheel [Rh7(PiPr3) 6H18][BArF4]2 (shown), which resembles a planar Rh(111) surface with 18 hydride ligands, was obtained together with [Rh8(PiPr3)6H16] [BArF4]2 from the reaction of [Rh(PiPr 3)2(nbd)][BArF4] and [Rh(nbd) 2][BArF4] with hydrogen (ArF = C6H3(CF3)2, nbd = norbornadiene). Some of the H ligands are located in threefold hollows between Rh centers and thus mimic the orientation of atomic hydrogen adsorbed on Rh(111). (Figure Presented). {\textcopyright} 2007 Wiley-VCH Verlag GmbH & Co. KGaA.",

keywords = "Cluster compounds, Density functional calculations, Hydride ligands, Hydrogen, Rhodium",

author = "Brayshaw, {Simon K.} and Green, {Jennifer C.} and Ruth Edge and McInnes, {Eric J L} and Raithby, {Paul R.} and Warren, {John E.} and Weller, {Andrew S.}",

note = "Brayshaw, Simon K. Green, Jennifer C. Edge, Ruth McInnes, Eric J. L. Raithby, Paul R. Warren, John E. Weller, Andrew S. 28 WILEY-V C H VERLAG GMBH WEINHEIM 223GQ",

year = "2007",

doi = "10.1002/anie.200703069",

language = "English",

volume = "46",

pages = "7844--7848",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley & Sons Ltd",

number = "41",

}

TY - JOUR

T1 - [Rh7(PiPr3)6H18][BAr F4]2: A molecular Rh(111) surface decorated with 18 hydrogen atoms

AU - Brayshaw, Simon K.

AU - Green, Jennifer C.

AU - Edge, Ruth

AU - McInnes, Eric J L

AU - Raithby, Paul R.

AU - Warren, John E.

AU - Weller, Andrew S.

N1 - Brayshaw, Simon K. Green, Jennifer C. Edge, Ruth McInnes, Eric J. L. Raithby, Paul R. Warren, John E. Weller, Andrew S. 28 WILEY-V C H VERLAG GMBH WEINHEIM 223GQ

PY - 2007

Y1 - 2007

N2 - Heptarhodium wagon wheel [Rh7(PiPr3) 6H18][BArF4]2 (shown), which resembles a planar Rh(111) surface with 18 hydride ligands, was obtained together with [Rh8(PiPr3)6H16] [BArF4]2 from the reaction of [Rh(PiPr 3)2(nbd)][BArF4] and [Rh(nbd) 2][BArF4] with hydrogen (ArF = C6H3(CF3)2, nbd = norbornadiene). Some of the H ligands are located in threefold hollows between Rh centers and thus mimic the orientation of atomic hydrogen adsorbed on Rh(111). (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - Heptarhodium wagon wheel [Rh7(PiPr3) 6H18][BArF4]2 (shown), which resembles a planar Rh(111) surface with 18 hydride ligands, was obtained together with [Rh8(PiPr3)6H16] [BArF4]2 from the reaction of [Rh(PiPr 3)2(nbd)][BArF4] and [Rh(nbd) 2][BArF4] with hydrogen (ArF = C6H3(CF3)2, nbd = norbornadiene). Some of the H ligands are located in threefold hollows between Rh centers and thus mimic the orientation of atomic hydrogen adsorbed on Rh(111). (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - Cluster compounds

KW - Density functional calculations

KW - Hydride ligands

KW - Hydrogen

KW - Rhodium

U2 - 10.1002/anie.200703069

DO - 10.1002/anie.200703069

M3 - Article

SN - 1433-7851

VL - 46

SP - 7844

EP - 7848

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 41

ER -

[Rh7(PiPr3)6H18][BAr F4]2: A molecular Rh(111) surface decorated with 18 hydrogen atoms

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CCDC 652792: Experimental Crystal Structure Determination

CCDC 652793: Experimental Crystal Structure Determination

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