Samarium(II) - mediated linker cleavage - cyclization in fluorous synthesis: Reactions of samarium enolates

Karen M. James, Nigel Willetts, David J. Procter

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Sml2 has been used to cleave a sulfur linker and trigger cyclizations in strategies for the traceless fluorous synthesis of N-heterocycles. The studies give further Insights Into the reactivity of samarium enolates. © 2008 American Chemical Society.
    Original languageEnglish
    Pages (from-to)1203-1206
    Number of pages3
    JournalOrganic Letters
    Volume10
    Issue number6
    DOIs
    Publication statusPublished - 20 Mar 2008

    Keywords

    • PHASE ORGANIC-SYNTHESIS
    • CYCLATIVE-CAPTURE STRATEGY
    • SOLID-PHASE
    • CARBONYL-COMPOUNDS
    • N-HETEROCYCLES
    • IODIDE
    • REDUCTION
    • CHEMISTRY
    • SMI2
    • SEPARATION

    Fingerprint

    Dive into the research topics of 'Samarium(II) - mediated linker cleavage - cyclization in fluorous synthesis: Reactions of samarium enolates'. Together they form a unique fingerprint.

    Cite this