Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material

Mathew Savage; Yongqiang Cheng; Timothy L. Easun; Jennifer Eyley; Stephen P. Argent; Mark R. Warren; William Lewis; Claire Murray; Chiu C. Tang; Mark D. Frogley; Gianfelice Cinque; Junliang Sun; Svemir Rudić; Richard T. Murden; Michael J. Benham; Andrew N. Fitch; Alexander J. Blake; Anibal J. Ramirez-Cuesta; Sihai Yang; Martin Schröder

doi:10.1002/adma.201602338

Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material

Mathew Savage, Yongqiang Cheng, Timothy L. Easun, Jennifer Eyley, Stephen P. Argent, Mark R. Warren, William Lewis, Claire Murray, Chiu C. Tang, Mark D. Frogley, Gianfelice Cinque, Junliang Sun, Svemir Rudić, Richard T. Murden, Michael J. Benham, Andrew N. Fitch, Alexander J. Blake, Anibal J. Ramirez-Cuesta, Sihai Yang^*, Martin Schröder

^*Corresponding author for this work

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Abstract

Selective adsorption of SO2 is realized in a porous metal–organic framework material, and in-depth structural and spectroscopic investigations using X-rays, infrared, and neutrons define the underlying interactions that cause SO2 to bind more strongly than CO2 and N2.

Original language	English
Pages (from-to)	8705-8711
Journal	Advanced Materials
Volume	28
Issue number	39
Early online date	16 Aug 2016
DOIs	https://doi.org/10.1002/adma.201602338
Publication status	Published - 16 Aug 2016

Keywords

Carbon dioxide
Carboxylates
Indium
Metal-organic frameworks
Sulfur dioxide

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10.1002/adma.201602338

Savage_et_al-2016-Advanced_MaterialsFinal published version, 3.64 MBLicence: CC BY

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Savage, M., Cheng, Y., Easun, T. L., Eyley, J., Argent, S. P., Warren, M. R., Lewis, W., Murray, C., Tang, C. C., Frogley, M. D., Cinque, G., Sun, J., Rudić, S., Murden, R. T., Benham, M. J., Fitch, A. N., Blake, A. J., Ramirez-Cuesta, A. J., Yang, S., & Schröder, M. (2016). Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material. Advanced Materials, 28(39), 8705-8711. https://doi.org/10.1002/adma.201602338

@article{3becccf0aafc44c295fd1a525166dcfc,

title = "Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material",

abstract = "Selective adsorption of SO2 is realized in a porous metal–organic framework material, and in-depth structural and spectroscopic investigations using X-rays, infrared, and neutrons define the underlying interactions that cause SO2 to bind more strongly than CO2 and N2.",

keywords = "Carbon dioxide, Carboxylates, Indium, Metal-organic frameworks, Sulfur dioxide",

author = "Mathew Savage and Yongqiang Cheng and Easun, {Timothy L.} and Jennifer Eyley and Argent, {Stephen P.} and Warren, {Mark R.} and William Lewis and Claire Murray and Tang, {Chiu C.} and Frogley, {Mark D.} and Gianfelice Cinque and Junliang Sun and Svemir Rudi{\'c} and Murden, {Richard T.} and Benham, {Michael J.} and Fitch, {Andrew N.} and Blake, {Alexander J.} and Ramirez-Cuesta, {Anibal J.} and Sihai Yang and Martin Schr{\"o}der",

year = "2016",

month = aug,

day = "16",

doi = "10.1002/adma.201602338",

language = "English",

volume = "28",

pages = "8705--8711",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "John Wiley & Sons Ltd",

number = "39",

}

Savage, M, Cheng, Y, Easun, TL, Eyley, J, Argent, SP, Warren, MR, Lewis, W, Murray, C, Tang, CC, Frogley, MD, Cinque, G, Sun, J, Rudić, S, Murden, RT, Benham, MJ, Fitch, AN, Blake, AJ, Ramirez-Cuesta, AJ, Yang, S & Schröder, M 2016, 'Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material', Advanced Materials, vol. 28, no. 39, pp. 8705-8711. https://doi.org/10.1002/adma.201602338

TY - JOUR

T1 - Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material

AU - Savage, Mathew

AU - Cheng, Yongqiang

AU - Easun, Timothy L.

AU - Eyley, Jennifer

AU - Argent, Stephen P.

AU - Warren, Mark R.

AU - Lewis, William

AU - Murray, Claire

AU - Tang, Chiu C.

AU - Frogley, Mark D.

AU - Cinque, Gianfelice

AU - Sun, Junliang

AU - Rudić, Svemir

AU - Murden, Richard T.

AU - Benham, Michael J.

AU - Fitch, Andrew N.

AU - Blake, Alexander J.

AU - Ramirez-Cuesta, Anibal J.

AU - Yang, Sihai

AU - Schröder, Martin

PY - 2016/8/16

Y1 - 2016/8/16

N2 - Selective adsorption of SO2 is realized in a porous metal–organic framework material, and in-depth structural and spectroscopic investigations using X-rays, infrared, and neutrons define the underlying interactions that cause SO2 to bind more strongly than CO2 and N2.

AB - Selective adsorption of SO2 is realized in a porous metal–organic framework material, and in-depth structural and spectroscopic investigations using X-rays, infrared, and neutrons define the underlying interactions that cause SO2 to bind more strongly than CO2 and N2.

KW - Carbon dioxide

KW - Carboxylates

KW - Indium

KW - Metal-organic frameworks

KW - Sulfur dioxide

UR - http://www.scopus.com/inward/record.url?scp=84981744875&partnerID=8YFLogxK

U2 - 10.1002/adma.201602338

DO - 10.1002/adma.201602338

M3 - Article

AN - SCOPUS:84981744875

SN - 0935-9648

VL - 28

SP - 8705

EP - 8711

JO - Advanced Materials

JF - Advanced Materials

IS - 39

ER -

Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material

Abstract

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CCDC 1475893: Experimental Crystal Structure Determination

CCDC 1475894: Experimental Crystal Structure Determination

CCDC 1475895: Experimental Crystal Structure Determination

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Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material

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Keywords

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Datasets

CCDC 1475893: Experimental Crystal Structure Determination

CCDC 1475894: Experimental Crystal Structure Determination

CCDC 1475895: Experimental Crystal Structure Determination

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