Selective pairwise encapsulation using directional interactions.

Guzman Gil-Ramirez, Guzmán Gil-Ramírez, Marcos Chas, Pablo Ballester

    Research output: Contribution to journalArticlepeer-review

    Abstract

    Trimethylamine N-oxide and trimethylphosphine oxide guests are pairwise encapsulated in a dimeric capsule self-assembled from a tetraurea aryl extended calix[4]pyrrole. The capsule possesses polar functional groups in its interior capable of controlling the orientation of the included guests. A modest selectivity is observed during the encapsulation process that is beyond the controls of size or shape exclusion.
    Original languageEnglish
    JournalJournal of the American Chemical Society
    Volume132
    Issue number8
    DOIs
    Publication statusPublished - 3 Mar 2010

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