Self-assembly of heterobimetallic d-f hybrid complexes: Sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states

Simon J A Pope; Benjamin J. Coe; Stephen Faulkner; Elena V. Bichenkova; Xuan Yu; Kenneth T. Douglas

doi:10.1021/ja047523h

Self-assembly of heterobimetallic d-f hybrid complexes: Sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states

Simon J A Pope
, Benjamin J. Coe
, Stephen Faulkner
, Elena V. Bichenkova
, Xuan Yu
, Kenneth T. Douglas

Research output: Contribution to journal › Article › peer-review

Abstract

Carboxylate-bearing d-transition metal bipyridyls form ternary complexes with seven-coordinate lanthanide centers. The neodymium,- ytterbium-, and erbium-containing complexes exhibit lanthanide-centered emissions sensitized by the MLCT states of the d-block components. Copyright © 2004 American Chemical Society.

Original language	English
Pages (from-to)	9490-9491
Number of pages	1
Journal	Journal of the American Chemical Society
Volume	126
Issue number	31
DOIs	https://doi.org/10.1021/ja047523h
Publication status	Published - 11 Aug 2004

Keywords

Hydration (inner-sphere; self-assembly of heterobimetallic d-f hybrid complexes: sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states); Charge transfer state (metal-to-ligand; self-assembly of heterobimetallic d-f hybrid complexes: sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states); Excited state; Luminescence; NMR (self-assembly of heterobimetallic d-f hybrid complexes: sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states)

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10.1021/ja047523h

http://pubs.acs.org/cgi-bin/article.cgi/jacsat/2004/126/i31/pdf/ja047523h.pdf

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@article{90d847d1548b45b08d22a0b2fdc68ece,

title = "Self-assembly of heterobimetallic d-f hybrid complexes: Sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states",

abstract = "Carboxylate-bearing d-transition metal bipyridyls form ternary complexes with seven-coordinate lanthanide centers. The neodymium,- ytterbium-, and erbium-containing complexes exhibit lanthanide-centered emissions sensitized by the MLCT states of the d-block components. Copyright {\textcopyright} 2004 American Chemical Society.",

keywords = "Hydration (inner-sphere; self-assembly of heterobimetallic d-f hybrid complexes: sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states); Charge transfer state (metal-to-ligand; self-assembly of heterobimetallic d-f hybrid complexes: sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states); Excited state; Luminescence; NMR (self-assembly of heterobimetallic d-f hybrid complexes: sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states)",

author = "Pope, \{Simon J A\} and Coe, \{Benjamin J.\} and Stephen Faulkner and Bichenkova, \{Elena V.\} and Xuan Yu and Douglas, \{Kenneth T.\}",

year = "2004",

month = aug,

day = "11",

doi = "10.1021/ja047523h",

language = "English",

volume = "126",

pages = "9490--9491",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "31",

}

Self-assembly of heterobimetallic d-f hybrid complexes: Sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states. / Pope, Simon J A; Coe, Benjamin J.; Faulkner, Stephen et al.
In: Journal of the American Chemical Society, Vol. 126, No. 31, 11.08.2004, p. 9490-9491.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Self-assembly of heterobimetallic d-f hybrid complexes: Sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states

AU - Pope, Simon J A

AU - Coe, Benjamin J.

AU - Faulkner, Stephen

AU - Bichenkova, Elena V.

AU - Yu, Xuan

AU - Douglas, Kenneth T.

PY - 2004/8/11

Y1 - 2004/8/11

N2 - Carboxylate-bearing d-transition metal bipyridyls form ternary complexes with seven-coordinate lanthanide centers. The neodymium,- ytterbium-, and erbium-containing complexes exhibit lanthanide-centered emissions sensitized by the MLCT states of the d-block components. Copyright © 2004 American Chemical Society.

AB - Carboxylate-bearing d-transition metal bipyridyls form ternary complexes with seven-coordinate lanthanide centers. The neodymium,- ytterbium-, and erbium-containing complexes exhibit lanthanide-centered emissions sensitized by the MLCT states of the d-block components. Copyright © 2004 American Chemical Society.

KW - Hydration (inner-sphere; self-assembly of heterobimetallic d-f hybrid complexes: sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states); Charge transfer state (metal-to-ligand; self-assembly of heterobimetallic

U2 - 10.1021/ja047523h

DO - 10.1021/ja047523h

M3 - Article

SN - 0002-7863

VL - 126

SP - 9490

EP - 9491

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 31

ER -

Self-assembly of heterobimetallic d-f hybrid complexes: Sensitization of lanthanide luminescence by d-block metal-to-ligand charge-transfer excited states

Abstract

Keywords

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