Sensitive absorptive refocused scalar correlation NMR spectroscopy in solids

Daniel Lee; Jochem Struppe; Douglas W. Elliott; Leonard J. Mueller; Jeremy J. Titman

doi:10.1039/b818867j

Sensitive absorptive refocused scalar correlation NMR spectroscopy in solids

Daniel Lee, Jochem Struppe, Douglas W. Elliott, Leonard J. Mueller, Jeremy J. Titman

CE - Academic & Research

Research output: Contribution to journal › Article › peer-review

Abstract

A new two-dimensional NMR experiment is described which is suitable for obtaining magic angle spinning (MAS) scalar correlation spectra in solids. The new experiment has several advantages, including increased cross peak intensities, coupled with good suppression of the diagonal. Its utility is demonstrated via assignments of the carbon-13 MAS spectra of progesterone at natural abundance and of the polymer phase of 50%-U-13C-CsC60.

Original language	English
Pages (from-to)	3547-3553
Number of pages	7
Journal	Physical Chemistry Chemical Physics
Volume	11
Issue number	18
DOIs	https://doi.org/10.1039/b818867j
Publication status	Published - 14 May 2009

Access to Document

10.1039/b818867j

Cite this

@article{529e4b4bb70f4ec0838ae972bcf25b2b,

title = "Sensitive absorptive refocused scalar correlation NMR spectroscopy in solids",

abstract = "A new two-dimensional NMR experiment is described which is suitable for obtaining magic angle spinning (MAS) scalar correlation spectra in solids. The new experiment has several advantages, including increased cross peak intensities, coupled with good suppression of the diagonal. Its utility is demonstrated via assignments of the carbon-13 MAS spectra of progesterone at natural abundance and of the polymer phase of 50%-U-13C-CsC60.",

author = "Daniel Lee and Jochem Struppe and Elliott, {Douglas W.} and Mueller, {Leonard J.} and Titman, {Jeremy J.}",

year = "2009",

month = may,

day = "14",

doi = "10.1039/b818867j",

language = "English",

volume = "11",

pages = "3547--3553",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

publisher = "Royal Society of Chemistry",

number = "18",

}

TY - JOUR

T1 - Sensitive absorptive refocused scalar correlation NMR spectroscopy in solids

AU - Lee, Daniel

AU - Struppe, Jochem

AU - Elliott, Douglas W.

AU - Mueller, Leonard J.

AU - Titman, Jeremy J.

PY - 2009/5/14

Y1 - 2009/5/14

N2 - A new two-dimensional NMR experiment is described which is suitable for obtaining magic angle spinning (MAS) scalar correlation spectra in solids. The new experiment has several advantages, including increased cross peak intensities, coupled with good suppression of the diagonal. Its utility is demonstrated via assignments of the carbon-13 MAS spectra of progesterone at natural abundance and of the polymer phase of 50%-U-13C-CsC60.

AB - A new two-dimensional NMR experiment is described which is suitable for obtaining magic angle spinning (MAS) scalar correlation spectra in solids. The new experiment has several advantages, including increased cross peak intensities, coupled with good suppression of the diagonal. Its utility is demonstrated via assignments of the carbon-13 MAS spectra of progesterone at natural abundance and of the polymer phase of 50%-U-13C-CsC60.

UR - http://dx.doi.org/10.1039/b818867j

U2 - 10.1039/b818867j

DO - 10.1039/b818867j

M3 - Article

SN - 1463-9076

VL - 11

SP - 3547

EP - 3553

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 18

ER -

Sensitive absorptive refocused scalar correlation NMR spectroscopy in solids

Abstract

Access to Document

Other files and links

Fingerprint

Cite this