Sequential formation of [Ru(IPr)2(CO)H(OH2)] + and [Ru(IPr)(η6-6H6)(CO)H] + upon protonation of Ru(IPr)2(CO)H(OH) (IPr = l,3-bis(2,6- diisopropylphenyl)imidazol-2-ylidene)

Oily Saker; Mary F. Mahon; John E. Warren; Michael K. Whittlesey

doi:10.1021/om801150v

Sequential formation of [Ru(IPr)2(CO)H(OH2)] + and [Ru(IPr)(η6-6H6)(CO)H] + upon protonation of Ru(IPr)2(CO)H(OH) (IPr = l,3-bis(2,6- diisopropylphenyl)imidazol-2-ylidene)

Oily Saker, Mary F. Mahon, John E. Warren, Michael K. Whittlesey

Research output: Contribution to journal › Article › peer-review

Abstract

Protonation of the N-heterocyclic carbene (NHC) complex Ru(IPr) 2(CO)H(OH) (IPr = l,3-bis(2,6-diisopropy-lphenyl)imidazol-2-ylidene) with HBF4 OEt2 in thf affords the cationic aqua hydride complex [Ru(IPr)2(CO)H(OH2)](BF2), whereas if the solvent is changed to benzene, loss of imidazolium salt and H20 occurs to leave the 12e fragment [Ru(IPr)-(CO)H]+, which is isolated as the cationic arene species [Ru(IPr)(η6- C6H 6)(CO)H](BF6). © 2009 American Chemical Society.

Original language	English
Pages (from-to)	1976-1979
Number of pages	3
Journal	Organometallics
Volume	28
Issue number	6
DOIs	https://doi.org/10.1021/om801150v
Publication status	Published - 23 Mar 2009

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http://pubs.acs.org/doi/pdfplus/10.1021/om801150v

CCDC 711770: Experimental Crystal Structure Determination
Saker, O. (Contributor), Mahon, M. F. (Contributor), Warren, J. (Contributor) & Whittlesey, M. K. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2009
DOI: 10.5517/ccrwnbl, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrwnbl&sid=DataCite
Dataset
CCDC 711771: Experimental Crystal Structure Determination
Saker, O. (Contributor), Mahon, M. F. (Contributor), Warren, J. (Contributor) & Whittlesey, M. K. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2009
DOI: 10.5517/ccrwncm, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrwncm&sid=DataCite
Dataset
CCDC 711772: Experimental Crystal Structure Determination
Saker, O. (Contributor), Mahon, M. F. (Contributor), Warren, J. (Contributor) & Whittlesey, M. K. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2009
DOI: 10.5517/ccrwndn, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccrwndn&sid=DataCite
Dataset

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@article{9d67e01184fa4b2a84cc98ff51e58df4,

title = "Sequential formation of [Ru(IPr)2(CO)H(OH2)] + and [Ru(IPr)(η6-6H6)(CO)H] + upon protonation of Ru(IPr)2(CO)H(OH) (IPr = l,3-bis(2,6- diisopropylphenyl)imidazol-2-ylidene)",

abstract = "Protonation of the N-heterocyclic carbene (NHC) complex Ru(IPr) 2(CO)H(OH) (IPr = l,3-bis(2,6-diisopropy-lphenyl)imidazol-2-ylidene) with HBF4 OEt2 in thf affords the cationic aqua hydride complex [Ru(IPr)2(CO)H(OH2)](BF2), whereas if the solvent is changed to benzene, loss of imidazolium salt and H20 occurs to leave the 12e fragment [Ru(IPr)-(CO)H]+, which is isolated as the cationic arene species [Ru(IPr)(η6- C6H 6)(CO)H](BF6). {\textcopyright} 2009 American Chemical Society.",

author = "Oily Saker and Mahon, {Mary F.} and Warren, {John E.} and Whittlesey, {Michael K.}",

note = "6",

year = "2009",

month = mar,

day = "23",

doi = "10.1021/om801150v",

language = "English",

volume = "28",

pages = "1976--1979",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "6",

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TY - JOUR

T1 - Sequential formation of [Ru(IPr)2(CO)H(OH2)] + and [Ru(IPr)(η6-6H6)(CO)H] + upon protonation of Ru(IPr)2(CO)H(OH) (IPr = l,3-bis(2,6- diisopropylphenyl)imidazol-2-ylidene)

AU - Saker, Oily

AU - Mahon, Mary F.

AU - Warren, John E.

AU - Whittlesey, Michael K.

N1 - 6

PY - 2009/3/23

Y1 - 2009/3/23

N2 - Protonation of the N-heterocyclic carbene (NHC) complex Ru(IPr) 2(CO)H(OH) (IPr = l,3-bis(2,6-diisopropy-lphenyl)imidazol-2-ylidene) with HBF4 OEt2 in thf affords the cationic aqua hydride complex [Ru(IPr)2(CO)H(OH2)](BF2), whereas if the solvent is changed to benzene, loss of imidazolium salt and H20 occurs to leave the 12e fragment [Ru(IPr)-(CO)H]+, which is isolated as the cationic arene species [Ru(IPr)(η6- C6H 6)(CO)H](BF6). © 2009 American Chemical Society.

AB - Protonation of the N-heterocyclic carbene (NHC) complex Ru(IPr) 2(CO)H(OH) (IPr = l,3-bis(2,6-diisopropy-lphenyl)imidazol-2-ylidene) with HBF4 OEt2 in thf affords the cationic aqua hydride complex [Ru(IPr)2(CO)H(OH2)](BF2), whereas if the solvent is changed to benzene, loss of imidazolium salt and H20 occurs to leave the 12e fragment [Ru(IPr)-(CO)H]+, which is isolated as the cationic arene species [Ru(IPr)(η6- C6H 6)(CO)H](BF6). © 2009 American Chemical Society.

U2 - 10.1021/om801150v

DO - 10.1021/om801150v

M3 - Article

VL - 28

SP - 1976

EP - 1979

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 6

ER -

Sequential formation of [Ru(IPr)2(CO)H(OH2)] + and [Ru(IPr)(η6-6H6)(CO)H] + upon protonation of Ru(IPr)2(CO)H(OH) (IPr = l,3-bis(2,6- diisopropylphenyl)imidazol-2-ylidene)

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CCDC 711770: Experimental Crystal Structure Determination

CCDC 711771: Experimental Crystal Structure Determination

CCDC 711772: Experimental Crystal Structure Determination

Cite this