Silylamides: towards a half-century of stabilising remarkable f-element chemistry

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    Abstract

    This review highlights some of the outstanding contributions to f-element chemistry that have been supported by monodentate silylamide ligands over the past 45 years, since Bradley reported the first 3-coordinate lanthanide (Ln) complexes, [Ln(Nʺ)3] (Nʺ = {N(SiMe3)2}) in 1972. As well as providing a historical perspective, this review presents a plethora of monodentate silylamide f-element complexes with significant geometries, bonding motifs, physical properties and reactivity profiles.
    Original languageEnglish
    Title of host publicationOrganometallic Chemistry
    PublisherRoyal Society of Chemistry
    Volume41
    ISBN (Electronic)978-1-78801-220-1
    ISBN (Print)978-1-78262-416-5
    DOIs
    Publication statusPublished - 2017

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