Silylamides: towards a half-century of stabilising remarkable f-element chemistry

Conrad Goodwin; David Mills

doi:10.1039/9781782626923-00123

Silylamides: towards a half-century of stabilising remarkable f-element chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

This review highlights some of the outstanding contributions to f-element chemistry that have been supported by monodentate silylamide ligands over the past 45 years, since Bradley reported the first 3-coordinate lanthanide (Ln) complexes, [Ln(Nʺ)₃] (Nʺ = {N(SiMe₃)₂}) in 1972. As well as providing a historical perspective, this review presents a plethora of monodentate silylamide f-element complexes with significant geometries, bonding motifs, physical properties and reactivity profiles.

Original language	English
Title of host publication	Organometallic Chemistry
Publisher	Royal Society of Chemistry
Volume	41
ISBN (Electronic)	978-1-78801-220-1
ISBN (Print)	978-1-78262-416-5
DOIs	https://doi.org/10.1039/9781782626923-00123
Publication status	Published - 2017

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abstract = "This review highlights some of the outstanding contributions to f-element chemistry that have been supported by monodentate silylamide ligands over the past 45 years, since Bradley reported the first 3-coordinate lanthanide (Ln) complexes, [Ln(Nʺ)3] (Nʺ = {N(SiMe3)2}) in 1972. As well as providing a historical perspective, this review presents a plethora of monodentate silylamide f-element complexes with significant geometries, bonding motifs, physical properties and reactivity profiles.",

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Silylamides: towards a half-century of stabilising remarkable f-element chemistry

Abstract

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