Single molecule magnetism in a family of mononuclear ??-diketonate lanthanide(III) complexes: rationalization of magnetic anisotropy in complexes of low symmetry

Nicholas F Chilton; Stuart K Langley; Boujemaa Moubaraki; Alessandro Soncini; Stuart R Batten; Keith S Murray

doi:10.1039/C3SC22300K

Single molecule magnetism in a family of mononuclear ??-diketonate lanthanide(III) complexes: rationalization of magnetic anisotropy in complexes of low symmetry

Nicholas F Chilton, Stuart K Langley, Boujemaa Moubaraki, Alessandro Soncini, Stuart R Batten, Keith S Murray

Research output: Contribution to journal › Article › peer-review

Abstract

The use of an amino-pyridyl substituted ??-diketone, N-(2-pyridyl)-ketoacetamide (paaH), has allowed for the isolation of two new families of isostructural mononuclear lanthanide complexes with general formulae: [Ln(paaH*)2(H2O)4][Cl]3??2H2O (Ln = Gd (1), Tb (2), Dy (3), Ho (4), Er (5) and Y (6)) and [Ln(paaH*)2(NO3)

Original language	English
Pages (from-to)	1719-1730
Number of pages	12
Journal	Chemical Science
Volume	4
DOIs	https://doi.org/10.1039/C3SC22300K
Publication status	Published - Jan 2013

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http://pubs.rsc.org/en/content/articlelanding/2013/sc/c3sc22300k

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title = "Single molecule magnetism in a family of mononuclear ??-diketonate lanthanide(III) complexes: rationalization of magnetic anisotropy in complexes of low symmetry",

abstract = "The use of an amino-pyridyl substituted ??-diketone, N-(2-pyridyl)-ketoacetamide (paaH), has allowed for the isolation of two new families of isostructural mononuclear lanthanide complexes with general formulae: [Ln(paaH*)2(H2O)4][Cl]3??2H2O (Ln = Gd (1), Tb (2), Dy (3), Ho (4), Er (5) and Y (6)) and [Ln(paaH*)2(NO3)",

author = "Chilton, {Nicholas F} and Langley, {Stuart K} and Boujemaa Moubaraki and Alessandro Soncini and Batten, {Stuart R} and Murray, {Keith S}",

year = "2013",

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doi = "10.1039/C3SC22300K",

language = "English",

volume = "4",

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journal = "Chemical Science",

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publisher = "Royal Society of Chemistry",

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T1 - Single molecule magnetism in a family of mononuclear ??-diketonate lanthanide(III) complexes: rationalization of magnetic anisotropy in complexes of low symmetry

AU - Chilton, Nicholas F

AU - Langley, Stuart K

AU - Moubaraki, Boujemaa

AU - Soncini, Alessandro

AU - Batten, Stuart R

AU - Murray, Keith S

PY - 2013/1

Y1 - 2013/1

N2 - The use of an amino-pyridyl substituted ??-diketone, N-(2-pyridyl)-ketoacetamide (paaH), has allowed for the isolation of two new families of isostructural mononuclear lanthanide complexes with general formulae: [Ln(paaH*)2(H2O)4][Cl]3??2H2O (Ln = Gd (1), Tb (2), Dy (3), Ho (4), Er (5) and Y (6)) and [Ln(paaH*)2(NO3)

AB - The use of an amino-pyridyl substituted ??-diketone, N-(2-pyridyl)-ketoacetamide (paaH), has allowed for the isolation of two new families of isostructural mononuclear lanthanide complexes with general formulae: [Ln(paaH*)2(H2O)4][Cl]3??2H2O (Ln = Gd (1), Tb (2), Dy (3), Ho (4), Er (5) and Y (6)) and [Ln(paaH*)2(NO3)

U2 - 10.1039/C3SC22300K

DO - 10.1039/C3SC22300K

M3 - Article

SN - 2041-6520

VL - 4

SP - 1719

EP - 1730

JO - Chemical Science

JF - Chemical Science

ER -

Single molecule magnetism in a family of mononuclear ??-diketonate lanthanide(III) complexes: rationalization of magnetic anisotropy in complexes of low symmetry

Abstract

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