Abstract
Single-molecule magnets: Straightforward oxidation of a triamidoamine uranium(III) complex with trimethyl-N-oxide affords a uranium(V) terminal mono-oxo complex which is the first clear-cut example of a uranium(V) single-molecule magnet (SMM). This monometallic complex unambiguously shows that a strongly axially ligated and thus anisotropic ligand field can be used to overcome the limited magnetic anisotropy of uranium(V). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| Original language | English |
|---|---|
| Pages (from-to) | 4921-4924 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 52 |
| Issue number | 18 |
| DOIs | |
| Publication status | Published - 26 Apr 2013 |
Keywords
- magnetism
- single-molecule magnets
- slow relaxation
- uranium
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CCDC 922773: Experimental Crystal Structure Determination
King, D. M. (Contributor), Tuna, F. (Contributor), McMaster, J. (Contributor), Lewis, W. (Contributor), Blake, A. J. (Contributor), Mcinnes, E. (Contributor) & Liddle, S. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/cczz6w0, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cczz6w0&sid=DataCite
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