Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides

Scott A. Sulway; Richard A. Layfield; Floriana Tuna; Wolfgang Wernsdorfer; Richard E P Winpenny

doi:10.1039/c1cc14643b

Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides

Scott A. Sulway, Richard A. Layfield, Floriana Tuna, Wolfgang Wernsdorfer, Richard E P Winpenny

Research output: Contribution to journal › Article › peer-review

Abstract

[Cp 2Dy(thf)(μ-Cl)] 2 (2) was synthesized from [Cp 2Dy(μ-Cl)] n, which crystalizes as two polymorphs, with n = 2 (1a) or ∞ (1b). All three compounds show slow relaxation of magnetization, and in 2 the quantum tunnelling was found to be exchange-biased. © 2012 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	1508-1510
Number of pages	2
Journal	Chemical Communications
Volume	48
Issue number	10
DOIs	https://doi.org/10.1039/c1cc14643b
Publication status	Published - 1 Feb 2012

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10.1039/c1cc14643b

CCDC 833439: Experimental Crystal Structure Determination
Sulway, S. A. (Contributor), Layfield, R. (Contributor), Tuna, F. (Contributor), Wernsdorfer, W. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012
DOI: 10.5517/ccwz847, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwz847&sid=DataCite
Dataset
CCDC 833437: Experimental Crystal Structure Determination
Sulway, S. A. (Contributor), Layfield, R. (Contributor), Tuna, F. (Contributor), Wernsdorfer, W. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012
DOI: 10.5517/ccwz825, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwz825&sid=DataCite
Dataset
CCDC 833438: Experimental Crystal Structure Determination
Sulway, S. A. (Contributor), Layfield, R. (Contributor), Tuna, F. (Contributor), Wernsdorfer, W. (Contributor) & Winpenny, R. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2012
DOI: 10.5517/ccwz836, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccwz836&sid=DataCite
Dataset

Cite this

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title = "Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides",

abstract = "[Cp 2Dy(thf)(μ-Cl)] 2 (2) was synthesized from [Cp 2Dy(μ-Cl)] n, which crystalizes as two polymorphs, with n = 2 (1a) or ∞ (1b). All three compounds show slow relaxation of magnetization, and in 2 the quantum tunnelling was found to be exchange-biased. {\textcopyright} 2012 The Royal Society of Chemistry.",

author = "Sulway, {Scott A.} and Layfield, {Richard A.} and Floriana Tuna and Wolfgang Wernsdorfer and Winpenny, {Richard E P}",

year = "2012",

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doi = "10.1039/c1cc14643b",

language = "English",

volume = "48",

pages = "1508--1510",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides

AU - Sulway, Scott A.

AU - Layfield, Richard A.

AU - Tuna, Floriana

AU - Wernsdorfer, Wolfgang

AU - Winpenny, Richard E P

PY - 2012/2/1

Y1 - 2012/2/1

N2 - [Cp 2Dy(thf)(μ-Cl)] 2 (2) was synthesized from [Cp 2Dy(μ-Cl)] n, which crystalizes as two polymorphs, with n = 2 (1a) or ∞ (1b). All three compounds show slow relaxation of magnetization, and in 2 the quantum tunnelling was found to be exchange-biased. © 2012 The Royal Society of Chemistry.

AB - [Cp 2Dy(thf)(μ-Cl)] 2 (2) was synthesized from [Cp 2Dy(μ-Cl)] n, which crystalizes as two polymorphs, with n = 2 (1a) or ∞ (1b). All three compounds show slow relaxation of magnetization, and in 2 the quantum tunnelling was found to be exchange-biased. © 2012 The Royal Society of Chemistry.

U2 - 10.1039/c1cc14643b

DO - 10.1039/c1cc14643b

M3 - Article

SN - 1359-7345

VL - 48

SP - 1508

EP - 1510

JO - Chemical Communications

JF - Chemical Communications

IS - 10

ER -

Single-molecule magnetism in cyclopentadienyl-dysprosium chlorides

Abstract

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Datasets

CCDC 833439: Experimental Crystal Structure Determination

CCDC 833437: Experimental Crystal Structure Determination

CCDC 833438: Experimental Crystal Structure Determination

Cite this